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The alkali metal with the highest first enthalpy of ionization is

  • A.Cs
  • B.Rb
  • C.K
  • D.Na
  • E.Li

Answer: E

The alkali metal with the highest first ionization enthalpy is Li.

Down group 1 the atomic radius increases and the outer s electron is held less tightly, so the first ionization enthalpy falls: Li (520) > Na (496) > K (419) > Rb (403) > Cs (376 kJ mol−1).

Lithium, the smallest atom, has the highest value, and caesium the lowest.

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