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Which of the both sequences represent an increasing order of orbital energy ?

  • A.2p, 3s, 3p, 3d & 3s, 3p, 3d, 4s
  • B.3s, 3p, 3d, 4s & 4s, 5s, 6s, 7s
  • C.3s, 3p, 4s, 3d & 5s, 3d, 4f, 4p
  • D.3p, 4s, 3d, 4p & 2p, 3s, 3p, 4s

Answer: D

The sequences in increasing order are 3p, 4s, 3d, 4p & 2p, 3s, 3p, 4s.

By the (n + l) rule, orbitals fill in order of increasing n + l, and for equal n + l the one with lower n comes first: 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d and so on. Both sequences in option D follow this order.

Option A's second sequence puts 3d before 4s. Option B puts 3d before 4s in its first sequence. Option C's second sequence puts 5s before 3d and 4f before 4p, both reversed.

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