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How does a magnetic sector analyser separate ions?

  • A.By timing their flight along a field-free drift tube
  • B.By trapping them and ejecting them in order of mass
  • C.By curving their paths according to momentum
  • D.By filtering them with oscillating electric fields applied to four rods

Answer: C

A magnetic field bends each ion's path, and heavier ions curve less for the same accelerating voltage, so scanning the field brings each mass in turn onto the detector. The other three describe the quadrupole, the time-of-flight and the ion trap. Sector instruments give the highest resolution but are large and slow, which is why they have largely given way to the others outside specialist work. Naming the cost of a choice alongside its benefit is what turns a fact into a design decision.

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