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A three-dimensional classical Harmonic Oscillator is in thermal equilibrium with a heat reservoir at temperature T. Its average total energy would be :

  • A.6 \(k_{B}T\)
  • B.3/2 \(k_{B}T\)
  • C.\(k_{B}T\)
  • D.3 \(k_{B}T\)

Answer: D

The average total energy is 3 \(k_{B}T\).

The energy of a three-dimensional classical oscillator has six quadratic terms: three kinetic, \(p_{x}^{2}/2m\) and so on, and three potential, \(\frac{1}{2}kx^{2}\) and so on. By the equipartition theorem each quadratic term contributes \(\frac{1}{2}k_{B}T\):

\[ \langle E \rangle = 6 \times \frac{1}{2}k_{B}T = 3k_{B}T \]

\(\frac{3}{2}k_{B}T\) is the kinetic energy alone, as for a free particle. \(k_{B}T\) is a one-dimensional oscillator, and 6 \(k_{B}T\) wrongly gives each quadratic term a full \(k_{B}T\).

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