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Which of the following has the highest molar mass?
(Atomic mass: N=14, O=16, Ag=108, Pb=208, Na=23, H=1, K=39)

  • A.Silver nitrate
  • B.Lead nitrate
  • C.Ammonium nitrate
  • D.Sodium nitrate
  • E.Potassium nitrate

Answer: B

The highest molar mass belongs to Lead nitrate, Pb(NO3)2.

Each nitrate group, NO3, weighs 14 + 3 × 16 = 62. Lead is divalent, so its nitrate carries two of them:

\[ \begin{aligned} \mathrm{Pb(NO_{3})_{2}} &= 208 + 2 \times 62 = 332 \\ \mathrm{AgNO_{3}} &= 108 + 62 = 170 \end{aligned} \]

The others are lighter still: potassium nitrate 39 + 62 = 101, sodium nitrate 23 + 62 = 85, and ammonium nitrate NH4NO3 = 18 + 62 = 80. Silver nitrate is the trap, since silver is heavy, but it has only one nitrate group.

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