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The species that has 'T' shape is

  • A.\(\text{PCl}_{3}\)
  • B.\(\text{SOCl}_{2}\)
  • C.\(\text{BrF}_{3}\)
  • D.\([\text{IO}_{3}]^{-}\)

Answer: C

The T-shaped species is BrF3.

Bromine has 7 valence electrons. Three form bonds to fluorine and the remaining four make two lone pairs, giving five electron pairs in a trigonal bipyramid. The two lone pairs take equatorial positions, where they have more room, leaving the three fluorines in a T: two axial and one equatorial, with F-Br-F angles a little under 90°.

The other three have four electron pairs around the central atom, one of them a lone pair, and so are trigonal pyramidal: PCl3 (three P-Cl bonds and a lone pair), SOCl2 (S=O, two S-Cl and a lone pair on sulfur) and [IO3]− (three I-O bonds and a lone pair on iodine). None of them is T-shaped.

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