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As a particle's diameter falls, its surface to volume ratio

  • A.rises as the square of the diameter
  • B.remains unchanged, both scaling together
  • C.rises in inverse proportion to the diameter
  • D.falls in inverse proportion to the diameter

Answer: C

Correct answer: rises in inverse proportion to the diameter

For a sphere, \[ \frac{S}{V} = \frac{4\pi r^2}{\frac{4}{3}\pi r^3} = \frac{3}{r} = \frac{6}{d}. \] Area falls as the square of the size and volume as the cube, so their ratio goes as the inverse of the first power. This single relation underlies nanoscale catalysis, the tendency to agglomerate, and the depression of the melting point.

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