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Assertion: a metal nanoparticle melts below the bulk metal's melting point. Reason: surface atoms are less strongly bound than interior atoms.

  • A.the assertion is false although the reason offered is a true statement in itself
  • B.both the assertion and the reason are true and the reason explains the assertion
  • C.both the assertion and the reason are true but the reason does not explain the assertion
  • D.the assertion is true but the reason given for it is false

Answer: B

The smaller the particle the larger the proportion of those weakly bound surface atoms, so less energy is needed to disrupt the whole lattice. The depression can amount to hundreds of degrees for a particle a few nanometres across.

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