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A cooled tubular reactor for an exothermic reaction may develop a hot spot because

  • A.the tube itself is much too short
  • B.the reaction is an endothermic one
  • C.generation peaks where concentration is high
  • D.the coolant proves far too cold at the inlet

Answer: C

Correct answer: generation peaks where concentration is high

Reactant concentration is highest at the inlet, so that is where heat is generated fastest, while the cooling capacity per unit length is the same all along. The temperature therefore peaks somewhere near the front, and because the rate rises with temperature the peak can reinforce itself. Diluting the feed, staging the injection or grading the catalyst activity along the tube all flatten the profile.

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