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The wavefunction of a particle in one dimension is given by

\[ \psi(x) = \begin{cases} M, & -a \lt x \lt a \\ 0, & \text{otherwise.} \end{cases} \]

Here \(M\) and \(a\) are positive constants. If \(\varphi(p)\) is the corresponding momentum space wavefunction, which one of the following plots best represents \(|\varphi(p)|^{2}\)?

  • A.Plot of the squared momentum wavefunction against p: a smooth bell-shaped curve
  • B.Plot of the squared momentum wavefunction against p: a flat rectangular profile
  • C.Plot of the squared momentum wavefunction against p: a central peak with small decaying side lobes
  • D.Plot of the squared momentum wavefunction against p: a sharp cusp at the centre with long tails

Answer: C

The momentum distribution is a central peak with decaying side lobes, plot (C).

The momentum space wavefunction is the Fourier transform of the box function:

\[ \begin{aligned} \varphi(p) &= \frac{M}{\sqrt{2\pi\hbar}}\int_{-a}^{a} e^{-ipx/\hbar}\,dx \\ &= \frac{2M\hbar}{\sqrt{2\pi\hbar}}\,\frac{\sin(pa/\hbar)}{p} \end{aligned} \]

So \(|\varphi(p)|^{2} \propto \sin^{2}(pa/\hbar)/p^{2}\): a tall peak at \(p = 0\), zeros at \(p = n\pi\hbar/a\), and side lobes that shrink as \(1/p^{2}\).

A Gaussian (A) is the transform of a Gaussian, not of a box. A flat rectangle (B) would be the momentum distribution of a sinc-shaped wavefunction, the reverse transform. A cusp (D) is the transform of an exponential, such as \(e^{-|x|/a}\).

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