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A particle of mass m is confined in a three-dimensional cubical box of size L. The number of eigenstates of the Hamiltonian with energy \(\frac{19\hbar^{2}\pi^{2}}{mL^{2}}\) is :

  • A.10
  • B.4
  • C.3
  • D.9

Answer: D

There are 9 eigenstates with this energy.

The levels of a cubical box are

\[ \begin{aligned} E &= \frac{\pi^{2}\hbar^{2}}{2mL^{2}} \\ &\quad\times(n_{x}^{2} + n_{y}^{2} + n_{z}^{2}) \end{aligned} \]

so \(19\hbar^{2}\pi^{2}/mL^{2}\) needs \(n_{x}^{2} + n_{y}^{2} + n_{z}^{2} = 38\) with positive integers. The only ways to write 38 as a sum of three positive squares are

\[ \begin{aligned} 38 &= 36 + 1 + 1 \quad (6, 1, 1) \\ 38 &= 25 + 9 + 4 \quad (5, 3, 2) \end{aligned} \]

(6, 1, 1) can be arranged in 3 ways and (5, 3, 2) in 3! = 6 ways, giving 3 + 6 = 9 states. Stopping at one of the two sets gives 3 or 6, not an offered option; 10 and 4 come from miscounting the arrangements.

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