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The CORRECT order of electronegativity is

  • A.Al \(\gt\) Si \(\gt\) P \(\gt\) S
  • B.Al \(\gt\) S \(\gt\) Si \(\gt\) P
  • C.S \(\gt\) Si \(\gt\) Al \(\gt\) P
  • D.S \(\gt\) P \(\gt\) Si \(\gt\) Al

Answer: D

The correct order is S \(\gt\) P \(\gt\) Si \(\gt\) Al.

Across a period, electronegativity rises with nuclear charge, because the atoms shrink and hold their valence electrons more tightly. Al, Si, P and S are consecutive third-period elements, so electronegativity increases in that order; the Pauling values are roughly Al 1.6, Si 1.9, P 2.2, S 2.6.

Al \(\gt\) Si \(\gt\) P \(\gt\) S is the exact reverse. The two mixed orders put Si above P or P below Al, which no scale supports.

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