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A particle in a one-dimensional infinite potential well of width L is acted on by a perturbation

H′ = b(L - x)   \(0 \le x \le L\)
= 0   otherwise

First order correction to the first excited state is :

  • A.\(\frac{bL}{2}\)
  • B.\(\frac{bL}{\sqrt{2}}\)
  • C.2bL
  • D.bL

Answer: A

The first-order correction is \(\frac{bL}{2}\).

The first excited state of the well is \(\psi_{2} = \sqrt{\frac{2}{L}}\sin\frac{2\pi x}{L}\). The first-order correction is the expectation value of the perturbation:

\[ \begin{aligned} E^{(1)} &= \langle \psi_{2}|b(L - x)|\psi_{2} \rangle \\ &= bL - b\langle x \rangle \\ &= bL - b\frac{L}{2} = \frac{bL}{2} \end{aligned} \]

Every stationary state of the infinite well has \(|\psi|^{2}\) symmetric about the centre, so \(\langle x \rangle = L/2\) and the answer is the same for any level. Options bL and 2bL ignore the averaging of x, and \(bL/\sqrt{2}\) would come from mixing up the normalisation constant.

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