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A cooling curve for a mixture of eutectic composition resembles that of a pure substance in showing

  • A.no break or arrest of any kind
  • B.a break followed by a rise in temperature
  • C.a single horizontal arrest
  • D.two distinct breaks in slope

Answer: C

Correct answer: a single horizontal arrest

At the eutectic the system is invariant, so the temperature cannot fall while the latent heat is being given up, and the curve shows a flat arrest exactly as a pure substance does. The difference is microscopic rather than thermal: the solid formed is two phases intergrown, not one.

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