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Poly(vinyl chloride) requires a heat stabiliser during processing because it tends to

  • A.cross-link into an infusible network
  • B.eliminate hydrogen chloride
  • C.absorb moisture from the air
  • D.crystallise rapidly on cooling

Answer: B

Correct answer: eliminate hydrogen chloride

Heating PVC strips hydrogen chloride from the chain, leaving a conjugated sequence that absorbs visible light and discolours the material, and the acid released catalyses further elimination - so the degradation accelerates once it begins. Stabilisers based on metal soaps or organotins scavenge the acid and interrupt that autocatalysis, and without them PVC could not be processed at all.

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