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Increasing the proportion of sulphur in vulcanisation makes the rubber

  • A.lower in glass transition temperature
  • B.harder and less elastic
  • C.softer and more elastic
  • D.more soluble in hydrocarbons

Answer: B

Correct answer: harder and less elastic

Sulphur creates cross-links between the chains, and the more cross-links the less the chains can move relative to one another. A few per cent gives the soft elastic rubber of a tyre; thirty per cent or more gives ebonite, a hard rigid thermoset with no elasticity at all. The whole range from soft rubber to hard vulcanite is a matter of cross-link density.

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