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Green liquor is converted back to white liquor by

  • A.burning it in the recovery boiler
  • B.evaporating it to a smelt
  • C.bleaching it with chlorine dioxide
  • D.causticising with lime

Answer: D

Correct answer: causticising with lime

The smelt dissolved in water is green liquor, containing sodium carbonate. Adding slaked lime converts the carbonate to hydroxide and precipitates calcium carbonate: \[ \mathrm{Na_2CO_3 + Ca(OH)_2 \rightarrow 2NaOH + CaCO_3}. \] The lime mud is filtered off and calcined back to lime in a rotary kiln, so the lime circulates as well, and the restored white liquor returns to the digester.

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