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Reaction order differs from molecularity in that order is

  • A.always a whole number
  • B.the same as the stoichiometric coefficient
  • C.determined experimentally and need not be a whole number
  • D.always equal to the number of molecules in the equation

Answer: C

Correct answer: determined experimentally and need not be a whole number

Order is an empirical description of how the rate responds to concentration, obtained by fitting data, and it may be fractional, zero or even negative - a chain reaction commonly shows an order of one half, and a product-inhibited reaction a negative one. Molecularity counts the molecules taking part in one elementary step and is necessarily a small positive integer.

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