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In the following reaction, the change in oxidation state of Magnesium is

\(\mathrm{3Mg_{(s)} + N_{2(g)} \xrightarrow{\Delta} Mg_{3}N_{2(s)}}\)

  • A.0 to +2
  • B.0 to +3
  • C.0 to +4
  • D.0 to +6
  • E.0 to −2

Answer: A

Magnesium changes from 0 to +2.

Free magnesium metal, \(\mathrm{Mg_{(s)}}\), is an element in its standard state, so its oxidation state is 0. In magnesium nitride, \(\mathrm{Mg_{3}N_{2}}\), nitrogen is the more electronegative element and takes -3:

\[ \begin{aligned} 3x + 2(-3) &= 0 \\ x &= +2 \end{aligned} \]

So each magnesium atom loses two electrons and is oxidised, while nitrogen goes from 0 to -3 and is reduced. +3, +4 and +6 are not oxidation states of magnesium, a group 2 metal that only ever shows +2 in compounds, and a negative value would mean magnesium had gained electrons.

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