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When a small amount of copper powder is added to ZnSO4 solution, what would be the observation ?

  • A.Effervesence
  • B.Precipitation of a white solid
  • C.Formation of a blue solution
  • D.No reaction

Answer: D

The observation would be No reaction.

A metal can displace another from solution only if it is more reactive, that is, if it has a more negative reduction potential. Copper (E° Cu2+/Cu = +0.34 V) lies well below zinc (E° Zn2+/Zn = -0.76 V), so copper cannot reduce Zn2+. The reverse reaction, zinc displacing copper from CuSO4, is the one that happens.

A blue solution would require Cu2+ ions to form, which needs copper to be oxidised. Effervescence would need a gas such as hydrogen, which copper does not release from a neutral salt solution, and no white solid is formed.

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