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Three different crystallographic planes of a unit cell of a metal are given below (solid circles represent atom). The crystal system of the unit cell is

Three rectangles of atoms: plane (110) is 0.20 nm by 0.39 nm, plane (101) is 0.30 nm by 0.32 nm and plane (011) is 0.25 nm by 0.36 nm

  • A.triclinic
  • B.monoclinic
  • C.tetragonal
  • D.orthorhombic

Answer: D

The unit cell is orthorhombic.

Each plane is a rectangle whose sides are one cell edge and one face diagonal. The (110) plane contains the edge c and the diagonal \(\sqrt{a^{2}+b^{2}}\); (101) contains b and \(\sqrt{a^{2}+c^{2}}\); (011) contains a and \(\sqrt{b^{2}+c^{2}}\). Taking the short sides as edges, \(c = 0.20\), \(b = 0.30\) and \(a = 0.25\) nm. The diagonals then check out:

\[ \begin{aligned} \sqrt{0.25^{2}+0.30^{2}} &= 0.39\ \text{nm} \\ \sqrt{0.25^{2}+0.20^{2}} &= 0.32\ \text{nm} \\ \sqrt{0.30^{2}+0.20^{2}} &= 0.36\ \text{nm} \end{aligned} \]

All three planes are rectangles, so the axes are mutually perpendicular, and the three edges are all different: \(a \ne b \ne c\) with all angles 90°, which defines the orthorhombic system. Tetragonal needs two equal edges, while monoclinic and triclinic need at least one non-right angle, which would make some of these sections parallelograms.

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