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Which of the following gas has highest solubility in water at 298 K?

  • A.Formaldehyde
  • B.Methane
  • C.\(\mathrm{CO_{2}}\)
  • D.Vinyl chloride
  • E.Argon

Answer: A

The most soluble gas is formaldehyde.

Formaldehyde is a small polar molecule that forms hydrogen bonds with water and reacts with it to form the hydrate (methanediol); its 37-40% aqueous solution is sold as formalin. It is far more soluble than the other gases.

CO2 is only moderately soluble, vinyl chloride is slightly soluble, and the non-polar gases methane and argon are poorly soluble, their solubility governed by a large Henry's law constant.

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