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Why is absorbance preferred to transmittance for quantitative work?

  • A.It is proportional to concentration
  • B.It is easier for a detector to measure directly
  • C.It is independent of the path length used
  • D.It ranges from zero to one hundred per cent

Answer: A

Absorbance is linear in concentration, so a calibration curve is a straight line through the origin and a doubling of concentration doubles the reading. Transmittance is what the detector actually measures but falls exponentially with concentration. Absorbance depends on path length directly, and it has no upper bound. A quantity chosen because it linearises a relationship is worth the extra computation, and here the computation is a single logarithm. Framing the question as which quantity the change acts upon makes the answer follow without calculation.

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