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Why does polychromatic light cause a departure from the law?

  • A.The sample scatters shorter wavelengths more strongly
  • B.The source emits less at the analytical wavelength
  • C.Different wavelengths are absorbed to different degrees
  • D.The detector responds differently at each wavelength

Answer: C

The law holds for a single wavelength, and if the band admitted contains wavelengths of differing absorptivity, the less absorbed ones dominate the transmitted light and the curve bends downward. Detector response and scattering are separate effects. The remedy is a narrower bandwidth, which is why the slit width and the position of the analytical wavelength on a flat absorption maximum both matter for linearity. Reading the definition literally, rather than recalling a formula, is the reliable route through questions of this shape.

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