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An instrument has \( 0.1 \) per cent stray light. Its maximum measurable absorbance is about

  • A.1
  • B.0.1
  • C.5
  • D.3

Answer: D

Even with the sample absorbing everything, the stray light still reaches the detector:

\[ A_{max} = -\log_{10}(0.001) = 3 \]

giving about 3, and readings approaching it are increasingly compressed and non-linear. Reducing stray light by a factor of ten buys one more unit of absorbance, which is why high-absorbance work needs a double monochromator rather than a better detector.

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