Machine-translated by Google. Questions are authored in English.
Top

Discussion

How is a too-concentrated sample brought into that range?

  • A.Increase the source lamp's current
  • B.Measure at a wavelength off the absorption peak
  • C.Dilute it or use a shorter cell
  • D.Widen the monochromator's slit

Answer: C

Both dilution and a shorter path reduce the absorbance in proportion, bringing the reading into the range where photometric error is least. Slit width and lamp current affect the light available rather than the absorbance, and moving off the peak works but sacrifices the flat region that makes the reading insensitive to wavelength error. Two of the Beer-Lambert law's three terms are under the operator's control, and that is where the remedy lies. A limit that survives making every external component ideal is an intrinsic one, and worth knowing for that reason.

No comment is present. Be the first to comment.
Loading…

Post your comment

Please log in or register to post a comment.