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A wavelength of \( 2000 \ \mathrm{nm} \) corresponds to a wavenumber of

  • A.2000 per cm
  • B.500 per cm
  • C.20000 per cm
  • D.5000 per cm

Answer: D

Converting through centimetres:

\[ \begin{aligned} \tilde{\nu} &= \frac{10^{7}}{\lambda_{\mathrm{nm}}} \\ &= \frac{10^{7}}{2000} \\ &= 5000 \ \mathrm{cm^{-1}} \end{aligned} \]

giving 5000 per centimetre. The factor of ten to the seventh converts nanometres to centimetres, and remembering it as a single constant is quicker than working through the units each time.

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