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Discussion

A strong sharp absorption near 1700 reciprocal centimetres suggests the presence of a

  • A.carbon-carbon single bond
  • B.carbon-halogen bond
  • C.carbonyl group
  • D.hydroxyl group

Answer: C

Correct answer: carbonyl group

The carbon-oxygen double bond is strong and highly polar, so its stretch is both high in frequency and very intense - typically 1700 to 1750 reciprocal centimetres, and one of the easiest bands to recognise. The exact position discriminates within the family: an aldehyde or ketone near 1715, an ester near 1740, an amide near 1650, and conjugation lowering each by 20 to 30.

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