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A hollow cathode lamp is used in atomic absorption because it emits

  • A.the sharp resonance lines of the element sought
  • B.a continuous spectrum over a wide range
  • C.radiation only in the infrared region
  • D.a beam of constant intensity at every wavelength

Answer: A

Correct answer: the sharp resonance lines of the element sought

Atomic absorption lines are extremely narrow, so a continuous source filtered by an ordinary monochromator would deliver mostly light the atoms cannot absorb, and the sensitivity would be hopeless. A hollow cathode lamp whose cathode is made of the element emits exactly the lines that element absorbs, and narrower than the absorption profile. The price is that a separate lamp is needed for each element.

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