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Flame emission spectroscopy differs from atomic absorption in measuring light

  • A.transmitted through the unatomised sample
  • B.emitted by excited atoms in the flame
  • C.absorbed by ground-state atoms in the flame
  • D.scattered by particles in the flame

Answer: B

Correct answer: emitted by excited atoms in the flame

In flame emission the flame both atomises the sample and excites a fraction of the atoms thermally; the light they emit as they relax is measured, and no lamp is required. Atomic absorption measures instead the light removed from an external beam by the far larger population of ground-state atoms, which is why it is generally the more sensitive of the two for elements of high excitation energy.

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