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A solution giving an absorbance of 0.60 is diluted to one third of its concentration. Its absorbance becomes

  • A.0.60
  • B.0.30
  • C.0.20
  • D.1.80

Answer: C

Correct answer: 0.20

Absorbance is proportional to concentration, so diluting to one third divides it by three:

\[ \frac{0.60}{3} = 0.20 \]

This linearity is the whole basis of quantitative absorption spectrometry, and it is why absorbance rather than transmittance is the quantity plotted - transmittance would have gone from 25 to 63 per cent, which is not proportional to anything.

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