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Discussion

A compound's infrared spectrum shows a broad band at 3400 and a strong band at 1710 reciprocal centimetres. The compound is most likely a

  • A.carboxylic acid
  • B.simple ketone
  • C.primary amine
  • D.terminal alkyne

Answer: A

Correct answer: carboxylic acid

The two bands together settle it. A broad absorption at 3400 is a hydrogen-bonded O-H, and a strong band at 1710 is a carbonyl; a compound containing both is a carboxylic acid. A simple ketone would show the carbonyl without the hydroxyl, a primary amine would show N-H bands near 3300 without a carbonyl, and a terminal alkyne would show a sharp C-H near 3300 with a weak band near 2100 and no carbonyl at all.

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