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Let \(\rho(\vec{p}, \vec{q}, t)\) be the phase space density of an ensemble of a system. The Hamiltonian of the system is \(H(\vec{p}, \vec{q})\). If \(\{A, B\}\) denotes the Poisson bracket of \(A\) and \(B\), then

\(\dfrac{d\rho}{dt} = 0\)

implies

  • A.\(\dfrac{\partial\rho}{\partial t} = 0\)
  • B.\(\dfrac{\partial\rho}{\partial t} \propto \{\rho, H\}\)
  • C.\(\frac{\partial\rho}{\partial t}\propto\{\rho,\frac{\vec{p}\cdot\vec{q}}{2}\}\)
  • D.\(\frac{\partial\rho}{\partial t}\propto\{\rho,\frac{\vec{q}\cdot\vec{q}}{2}\}\)

Answer: B

The condition implies \(\dfrac{\partial\rho}{\partial t} \propto \{\rho, H\}\).

The total time derivative of a phase-space function along the motion is its explicit time derivative plus its Poisson bracket with the Hamiltonian:

\[ \begin{aligned} \frac{d\rho}{dt} &= \frac{\partial\rho}{\partial t} + \{\rho, H\} = 0 \\ \frac{\partial\rho}{\partial t} &= -\{\rho, H\} \end{aligned} \]

This is Liouville's theorem: the phase-space density is constant along trajectories, and its local rate of change is fixed by the bracket with H. ∂ρ/∂t = 0 holds only for a stationary ensemble, which dρ/dt = 0 alone does not guarantee. Brackets with p·q/2 or q·q/2 involve functions that are not the Hamiltonian of the system and do not generate its motion.

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