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Which of the following statement is not true about a catalyst?

  • A.It catalyses the spontaneous reactions
  • B.A small amount of the catalyst can catalyse the large amount of reactants.
  • C.It does not alter the Gibbs energy of a reaction.
  • D.It catalyses the non-spontaneous reactions.
  • E.It does not change the equilibrium constant of a reaction.

Answer: D

The untrue statement is It catalyses the non-spontaneous reactions.

A catalyst lowers the activation energy, providing a faster route, but it does not change \(\Delta G\) or the equilibrium constant. It can therefore only speed up reactions that are already thermodynamically feasible; it cannot make a non-spontaneous reaction go.

The other statements are true: catalysts speed up spontaneous reactions, a small amount suffices because it is regenerated, and it leaves both the Gibbs energy change and \(K\) unchanged.

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