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For a non-magnetic metal, which one of the following graphs best represents the behaviour of \(\frac{C}{T}\) vs. \(T^{2}\), where \(C\) is the heat capacity and \(T\) is the temperature?

  • A.Graph of C over T against T squared: a curve with a positive intercept that rises steeply
  • B.Graph of C over T against T squared: a straight line rising from a positive intercept
  • C.Graph of C over T against T squared: a curve rising quickly from the vertical axis and levelling off
  • D.Graph of C over T against T squared: a straight line rising from the origin

Answer: B

The plot is a straight line with a positive intercept, graph (B).

At low temperature the heat capacity of a non-magnetic metal is the sum of an electronic term, linear in \(T\), and the Debye phonon term, proportional to \(T^{3}\):

\[ \begin{aligned} C &= \gamma T + \beta T^{3} \\ \frac{C}{T} &= \gamma + \beta T^{2} \end{aligned} \]

Against \(T^{2}\) this is a straight line of slope \(\beta\) (from the phonons) cutting the axis at \(\gamma\) (from the conduction electrons). This is how the two contributions are separated experimentally.

A line through the origin (D) would describe an insulator with no electronic term. The two curved graphs do not follow from either term.

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