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If the temperature of 2 moles of krypton gas is increased from -11°C to 89°C at constant volume, then (specific heat at constant volume of krypton is CV)

  • A.work done on the gas is not zero
  • B.internal energy is not changed
  • C.work is done by the gas
  • D.amount of heat added is 200 \(C_{V}\)
  • E.internal energy is increased by 100 \(C_{V}\)

Answer: D

The amount of heat added is 200 CV.

At constant volume no work is done (\(W = P\Delta V = 0\)), so by the first law all the heat supplied goes into internal energy. The temperature rises by \(89 - (-11) = 100\) degrees, and with \(C_{V}\) the molar heat capacity at constant volume,

\[ Q = nC_{V}\Delta T = 2 \times C_{V} \times 100 = 200\,C_{V} \]

The internal energy also increases by \(200\,C_{V}\), not 100 \(C_{V}\), which forgets the 2 moles. No work is done on or by the gas, and the internal energy certainly changes, since the temperature rises.

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