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Consider the following statements :

Statement-1 : The ratio of Ni : Mg is highest in early formed crystals like olivine and shows a steady decline in late formed minerals.
Statement-2 : The nickel ion has essentially the same radius as magnesium.

Which of the following is correct with respect to the above statements ?

  • A.Both statement-1 and statement-2 are true and statement-1 is the correct explanation of statement-2
  • B.Both statement-1 and statement-2 are true and statement-1 is not the correct explaination of statement-2
  • C.Statement-1 is true but statement-2 is false
  • D.Statement-1 is false but statement-2 is true

Answer: B

The answer is Both statements are true and statement-1 is not the correct explanation of statement-2.

Statement-1 is true: nickel enters olivine readily, so the Ni : Mg ratio is highest in the earliest crystals and falls steadily in later minerals and residual liquids. Statement-2 is also true: the Ni2+ ion (about 0.69 Å) is very close in size to Mg2+ (about 0.72 Å), so it substitutes for magnesium.

The causal link runs the other way: the similar radius (statement-2), together with nickel's stronger preference for the olivine site, explains the early concentration of nickel (statement-1). Statement-1 does not explain statement-2, so option A, which claims it does, is wrong, and the options calling either statement false are wrong too.

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