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Assertion (A): A strongly exothermic reaction is often run semi-batch rather than as a full batch.
Reason (R): Feeding one reactant slowly limits the rate at which heat is released.

  • A.Both A and R are true, and R is the correct explanation of A
  • B.Both A and R are true, but R is not the correct explanation of A
  • C.A is true but R is false
  • D.A is false but R is true

Answer: A

Correct answer: Both A and R are true, and R is the correct explanation of A

Both are true and the reason gives the mechanism. With one reactant fed gradually only a little is present at any instant, so the reaction rate - and with it the heat release - is set by the feed rate rather than by the kinetics. The operator controls the exotherm with a valve, and closing it stops the heat almost at once, which a full batch charge does not allow.

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