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Assertion (A): Assertion: An auxochrome absorbs strongly in the ultraviolet on its own.

Reason (R): Reason: An auxochrome shifts a chromophore's band when attached to it.

Select the correct answer from the options below.

  • A.Both A and R are true, and R is the correct explanation of A
  • B.Both A and R are true, but R is not the correct explanation of A
  • C.A is true but R is false
  • D.A is false but R is true

Answer: D

The reason is true and is precisely why the assertion is false: an auxochrome is defined as a group with no accessible band of its own that nevertheless modifies a chromophore's. A group that did absorb strongly alone would be a chromophore. The two terms divide the substituents into those that produce absorption and those that only alter it, and that division is the whole point of having two words.

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