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GATE CH 2022: Chemical Engineering

  • Paper code: CH
  • Language: English
  • 42 pages
GATE CH 2022 question paper, GATE 2022, Chemical Engineering, page 1 of 42
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GATE 2022 General Aptitude (GA)
Q.1 – Q.5 Carry ONE mark each.


Q.1        Inhaling the smoke from a burning _________ could _________ you quickly.


      (A) tire / tier


      (B) tire / tyre


      (C) tyre / tire


      (D) tyre / tier




Q.2        A sphere of radius r cm is packed in a box of cubical shape.

           What should be the minimum volume (in cm3 ) of the box that can enclose the
           sphere?


      (A) r
          8


      (B) r


      (C) 2r


      (D) 8r




                                                                     Page 1
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Q.3       Pipes P and Q can fill a storage tank in full with water in 10 and 6 minutes,
          respectively. Pipe R draws the water out from the storage tank at a rate of 34
          litres per minute. P, Q and R operate at a constant rate.

          If it takes one hour to completely empty a full storage tank with all the pipes
          operating simultaneously, what is the capacity of the storage tank (in litres)?


      (A) 26.8


      (B) 60.0


      (C) 120.0


      (D) 127.5




                                                                      Page 2
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Q.4       Six persons P, Q, R, S, T and U are sitting around a circular table facing the
          center not necessarily in the same order. Consider the following statements:

             P sits next to S and T.
             Q sits diametrically opposite to P.
             The shortest distance between S and R is equal to the shortest distance
              between T and U.

          Based on the above statements, Q is a neighbor of


      (A) U and S


      (B) R and T


      (C) R and U


      (D) P and S




                                                                      Page 3
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Q.5       A building has several rooms and doors as shown in the top view of the building
          given below. The doors are closed initially.

          What is the minimum number of doors that need to be opened in order to go
          from the point P to the point Q?




      (A) 4


      (B) 3


      (C) 2


      (D) 1




                                                                   Page 4
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Q. 6 – Q. 10 Carry TWO marks each.




Q.6        Rice, a versatile and inexpensive source of carbohydrate, is a critical component
           of diet worldwide. Climate change, causing extreme weather, poses a threat to
           sustained availability of rice. Scientists are working on developing Green Super
           Rice (GSR), which is resilient under extreme weather conditions yet gives higher
           yields sustainably.

           Which one of the following is the CORRECT logical inference based on the
           information given in the above passage?


      (A) GSR is an alternative to regular rice, but it grows only in an extreme weather


      (B) GSR may be used in future in response to adverse effects of climate change


      (C) GSR grows in an extreme weather, but the quantity of produce is lesser than
           regular rice


      (D) Regular rice will continue to provide good yields even in extreme weather




                                                                      Page 5
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A game consists of spinning an arrow around a stationary disk as shown below.
Q.7
            When the arrow comes to rest, there are eight equally likely outcomes. It could
            come to rest in any one of the sectors numbered 1, 2, 3, 4, 5, 6, 7 or 8 as shown.

            Two such disks are used in a game where their arrows are independently spun.

            What is the probability that the sum of the numbers on the resulting sectors upon
            spinning the two disks is equal to 8 after the arrows come to rest?




      (A)    1
            16


      (B)    5
            64


      (C)    3
            32


      (D)    7
            64


                                                                         Page 6
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Q.8       Consider the following inequalities.

             (i)      3p − q < 4
             (ii)     3q − p < 12

          Which one of the following expressions below satisfies the above two
          inequalities?


      (A) p + q < 8


      (B) p + q = 8


      (C) 8 ≤ p + q < 16


      (D) p + q ≥ 16




                                                                   Page 7
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Q.9        Given below are three statements and four conclusions drawn based on the
           statements.

           Statement 1: Some engineers are writers.

           Statement 2: No writer is an actor.

           Statement 3: All actors are engineers.




           Conclusion I: Some writers are engineers.

           Conclusion II: All engineers are actors.

           Conclusion III: No actor is a writer.

           Conclusion IV: Some actors are writers.

           Which one of the following options can be logically inferred?


      (A) Only conclusion I is correct


      (B) Only conclusion II and conclusion III are correct


      (C) Only conclusion I and conclusion III are correct


      (D) Either conclusion III or conclusion IV is correct




                                                                     Page 8
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Q.10         Which one of the following sets of pieces can be assembled to form a square
             with a single round hole near the center? Pieces cannot overlap.


       (A)




       (B)




       (C)




       (D)




                                                                       Page 9
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GATE 2022 Chemical Engineering (CH)


Q.11 – Q.35 Carry ONE mark Each

Q.11    The value of (1 + i) , where i = √−1, is




(A)     −64i


(B)     64i


(C)     64


(D)     −64




                         x    1 3
 Q.12   Given matrix A = y    2 6 , the ordered pair (x, y) for which det(A) = 0 is
                         3    5 7




(A)     (1,1)


(B)     (1,2)


(C)     (2,2)


(D)     (2,1)




                                       Page 10
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Q.13    Let f(x) = e | | , where x is real. The value of    at x = −1 is




(A)     −e


(B)     e


(C)     1
            e

(D)     −1 e




Q.14    The value of the real variable x ≥ 0, which maximizes the function

        f(x) = x e     is




(A)     e


(B)     0


(C)     1
            e

(D)     1




                                         Page 11
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Q.15    For a single component system at vapor-liquid equilibrium, the extensive variables
        A, V, S and N denote the Helmholtz free energy, volume, entropy, and number of
        moles, respectively, in a given phase. If superscripts (v) and (l) denote the vapor
        and liquid phase, respectively, the relation that is NOT CORRECT is




(A)      ∂A( )               ∂A( )
                         =
         ∂V ( )   , ()
                             ∂V ( )   , ( )



(B)      ∂A( )               ∂A( )
                         =
         ∂N ( )   , ()
                             ∂N ( )   , ( )



(C)      A + PV ( )   A + PV ( )
                    =
           N            N


(D)      A + TS ( )   A + TS ( )
                    =
           N            N




Q.16    Consider turbulent flow in a pipe under isothermal conditions. Let r denote the
        radial coordinate and z denote the axial flow direction. On moving away from the
        wall towards the center of the pipe, the rz-component of the Reynolds stress




(A)     Increases and then decreases


(B)     Decreases and then increases


(C)     Remains unchanged


(D)     Only increases


                                              Page 12
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Q.17    Consider two stationary spherical pure water droplets of diameters d and 2d . CO2
        diffuses into the droplets from the surroundings. If the rate of diffusion of CO2 into
        the smaller droplet is W mol s-1, the rate of diffusion of CO2 into the larger droplet
        is




(A)     2W


(B)     4W


(C)     W


(D)     0.5W




Q.18    In soap manufacturing, the triglycerides present in oils and fats are hydrolyzed to
        mainly produce




(A)     Fatty acids and glycerol


(B)     Glycerol only


(C)     Fatty acids only


(D)     Glycerol and paraffins




                                          Page 13
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Q.19    The chemical formula of Glauber’s salt, used in the Kraft process, is




(A)     Na2CO3.10H2O


(B)     Na2S2O4.2H2O


(C)     Na2HPO4.2H2O


(D)     Na2SO4.10H2O




Q.20    Catalytic reforming is commonly used in the petroleum industry to improve fuel
        quality. The undesirable reaction in the catalytic reforming of naphtha is




(A)     Hydrocracking of paraffins


(B)     Dehydrogenation of naphthenes


(C)     Isomerization of naphthenes


(D)     Cyclization of paraffins




                                         Page 14
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Q.21    A control system on the jacket side of a reactor is shown in the figure. Pressurized
        water flows through the jacket to cool the reactor. The heated water flashes in the
        boiler. The exothermic reaction heat thus generates steam. Fresh boiler feed water
        (BFW) is added to make-up for the loss of water as steam. Assume that all control
        valves are air-to-open. The controller action, ‘direct’ or ‘reverse’, is defined with
        respect to the controller. Select the option that correctly specifies the action of the
        controllers.




(A)     PC: Reverse, LC: Direct, TC: Reverse


(B)     PC: Direct, LC: Reverse, TC: Direct


(C)     PC: Direct, LC: Reverse, TC: Reverse


(D)     PC: Reverse, LC: Direct, TC: Direct




                                          Page 15
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Q.22    Liquid flowing through a heat exchanger (HX) is heated. A bypass stream is
        provided to control the temperature of the heated exit stream. From the given
        plumbing options, the one that provides the most effective temperature control for
        large disturbances while avoiding vaporization in the heat exchanger is




(A)




(B)




(C)




(D)




                                        Page 16
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Q.23    The appropriate feedforward compensator, G , in the shown block diagram is




(A)             2 (8s + 1)
        G   =
                3 (5s + 1)


(B)               2 (8s + 1)
        G   =−
                  3 (5s + 1)


(C)             3 (5s + 1)
        G   =              e
                2 (8s + 1)


(D)               3 (5s + 1)
        G   =−               e
                  2 (8s + 1)




                                       Page 17
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Q.24    Choose the option that correctly pairs the given measurement devices with the
        quantities they measure.


                          Measurement                          Measured
                S No                                 S No
                            Device                             Quantity
                  I      Bourdon Gauge                 A      Temperature
                  II   Orifice Plate meter             B     Concentration
                 III       Pyrometer                   C        Pressure
                 IV        Colorimeter                 D        Flow rate
                  V       Pirani Gauge                 E      Liquid level



(A)     I-E II-C III-D IV-B V-A


(B)     I-C II-D III-A IV-B V-C


(C)     I-C II-D III-E IV-A V-D


(D)     I-D II-C III-A IV-E V-C




                                         Page 18
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Q.25    A simple distillation column is designed to separate an ideal binary mixture to
        specified distillate and bottoms purities at a given column pressure. If RRmin is the
        minimum reflux ratio for this separation, select the statement that is NOT
        CORRECT with regard to the variation in the total annualized cost (TAC) of the
        column with reflux ratio (RR).




(A)     TAC has a minimum with respect to RR


(B)     The sharpest rise in TAC occurs as RR approaches RRmin from above


(C)     The sharpest decrease in TAC occurs as RR approaches RRmin from above


(D)     TAC increases with RR for RR >> RRmin




Q.26    The reaction A → B is carried out isothermally on a porous catalyst. The intrinsic
        reaction rate is kC , where k is the rate constant and C is the concentration of A.
        If the reaction is strongly pore-diffusion controlled, the observed order of the
        reaction is




(A)     1


(B)     2


(C)     3
            2

(D)     √2


                                          Page 19
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Q.27    In an enzymatic reaction, an inhibitor (I) competes with the substrate (S) to bind
        with the enzyme (E), thereby reducing the rate of product (P) formation. The
        competitive inhibition follows the reaction mechanism shown below. Let [S] and
        [I] be the concentration of S and I, respectively, and r be the rate of consumption
        of S. Assuming pseudo-steady state, the correct plot of      vs [ ] is




(A)




(B)




(C)




(D)




                                         Page 20
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Q.28    The area of a circular field is 25 m2. The radius, r, is to be determined using the
        Newton-Raphson iterative method. For an initial guess of r = 2.500 m, the revised
        estimate of r after one iteration is ___________ m (rounded off to three decimal
        places).




Q.29    5 moles of liquid benzene, 8 moles of liquid toluene and 7 moles of liquid xylene
        are mixed at 25 °C and 1 bar. Assuming the formation of an ideal solution and using
        the universal gas constant R = 8.314 J mol-1 K-1, the total entropy change is
        __________ J K-1 (rounded off to one decimal place).




Q.30    A perfectly insulated double pipe heat exchanger is operating at steady state.
        Saturated steam enters the inner pipe at 100 °C and leaves as saturated water at
        100 °C. Cooling water enters the outer pipe at 75 °C and exits at 95 °C. The overall
        heat transfer coefficient is 1 kW m-2 K-1 and the heat transfer area is 1 m2. The
        average specific heat capacity of water at constant pressure is 4.2 kJ kg-1 K-1. The
        required cooling water flow rate is __________ kg s-1 (rounded off to two decimal
        places).




Q.31    Consider steady-state diffusion in a binary A-B liquid at constant temperature and
        pressure. The mole-fraction of A at two different locations is 0.8 and 0.1. Let N
        be the diffusive flux of A calculated assuming B to be non-diffusing, and N be the
        diffusive flux of A calculated assuming equimolar counter-diffusion. The quantity
        (        )
                   × 100 is____________(rounded off to one decimal place).




                                         Page 21
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Q.32    Consider interphase mass transfer of a species S between two immiscible liquids A
        and B. The interfacial mass transfer coefficient of S in liquid A is twice of that in
        liquid B. The equilibrium distribution of S between the liquids is given by
        y = 0.5y , where y and y are the mole-fractions of S in A and B, respectively.
        The bulk phase mole-fraction of S in A and B is 0.10 and 0.02, respectively. If the
        steady-state flux of S is estimated to be 10 kmol h-1 m-2, the mass transfer coefficient
        of S in A is ________ kmol h-1 m-2 (rounded off to one decimal place).




Q.33    A wet solid containing 20% (w/w) moisture (based on mass of bone-dry solid) is
        dried in a tray-dryer. The critical moisture content of the solid is 10% (w/w). The
        drying rate (kg m-2 s-1) is constant for the first 4 hours, and then decreases linearly
        to half the initial value in the next 1 hour. At the end of 5 hours of drying, the
        percentage moisture content of the solid is _________% (w/w) (rounded off to one
        decimal place).




Q.34    A process described by the transfer function
                                                        (10s  1)
                                           G p ( s) 
                                                         (5s  1)
        is forced by a unit step input at time t = 0. The output value immediately after the
        step input (at t = 0 ) is __________ (rounded off to the nearest integer).




                                           Page 22
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Q.35    A compressor with a life of 10 years costs Rs 10 lakhs. Its yearly operating cost is
        Rs 0.5 lakh. If the annual compound interest rate is 8%, the amount needed at
        present to fund perpetual operation of the compressor is Rs _________ lakhs
        (rounded to first decimal place).




                                         Page 23
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Q.36 – Q.65 Carry TWO marks Each

Q.36    The partial differential equation

                                              ∂u   1 ∂ u
                                                 =
                                              ∂t π ∂x
        where, t ≥ 0 and x ∈ [0,1], is subjected to the following initial and boundary
        conditions:

                                         u(x, 0) = sin ( πx)

                                                 u(0, t) = 0

                                                 u(1, t) = 0
                                   ( . , )
        The value of t at which              =      is
                                   ( . , )




(A)     1


(B)     e


(C)     π


(D)     1
            e




                                             Page 24
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Q.37    N moles of an ideal gas undergo a two-step process as shown in the figure. Let P,
        V and T denote the pressure, volume and temperature of the gas, respectively. The
        gas, initially at state-1 (P , V , T ), undergoes an isochoric (constant volume)
        process to reach state-A, and then undergoes an isobaric (constant pressure)
        expansion to reach state-2 (P , V , T ). For an ideal gas, C – C = NR, where C
        and C are the heat capacities at constant pressure and constant volume,
        respectively, and assumed to be temperature independent. The heat gained by the
        gas in the two-step process is given by




(A)     P (V − V ) + C (T − T )


(B)     P (V − V ) + C (T − T )


(C)     C (T − T ) + C (T − T )


(D)     P V −P V




                                        Page 25
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Q.38    A horizontal cylindrical water jet of diameter D = 2 cm strikes a vertical solid
        plate with a hole of diameter D = 1 cm, as shown in the figure. A part of the jet
        passes through the hole and the rest is deflected along the plate. The density of water
        is 1000 kg m-3. If the speed of the jet is 20 m s-1, the magnitude of the horizontal
        force, in N, required to hold the plate stationary is




(A)     30 


(B)     10 


(C)     20 


(D)     5




                                          Page 26
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Q.39    Consider a horizontal rod of radius aR (a < 1) in a stationary pipe of radius R.
        The rod is pulled coaxially at a constant velocity V as shown in the figure. The
        annular region is filled with a Newtonian incompressible fluid of viscosity  . The
        steady state fully developed axial velocity profile in the fluid is given by
                   ln( r / R )
        u (r )  V             , where r is the radial coordinate. Ignoring end effects, the
                     ln( a )
        magnitude of the pulling force per unit rod length is




(A)     V


(B)         2V
            ln(a )


(C)     0


(D)         V
            ln(a )




                                         Page 27
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Q.40    Consider a bare long copper wire of 1 mm diameter. Its surface temperature is T
        and the ambient temperature is T (T > T ). The wire is to be coated with a 2 mm
        thick insulation. The convective heat transfer coefficient is 20 W m-2 K-1. Assume
        that T and T remain unchanged. To reduce heat loss from the wire, the maximum
        allowed thermal conductivity of the insulating material, in W m-1 K-1, rounded off
        to two decimal places, is




(A)     0.02


(B)     0.04


(C)     0.10


(D)     0.01




Q.41    Two large parallel planar walls are maintained at 1000 K and 500 K. Parallel
        radiation shields are to be installed between the two walls. Assume that the
        emissivities of the walls and the shields are equal. If the melting temperature of the
        shields is 900 K, the maximum number of shield(s) that can be installed between
        the walls is (are)




(A)     1


(B)     0


(C)     2


(D)     3


                                          Page 28
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Q.42    Saturated steam condenses on a vertical plate maintained at a constant wall
        temperature. If x is the vertical distance from the top edge of the plate, then the local
        heat transfer coefficient ℎ(x) ∝ Г(x) / , where Г(x) is the local mass flow rate
        of the condensate per unit plate width. The ratio of the average heat transfer
        coefficient over the entire plate to the heat transfer coefficient at the bottom of the
        plate is




(A)     4


(B)     4/3


(C)     3/4


(D)     3




Q.43    Match the product in Group-1 with the manufacturing process in Group-2. The
        correct combination is


                           Group-1                         Group-2
                      P Nitric acid                I   Trona process
                      Q Phosphoric acid            II Twitchell process
                      R Potassium chloride         III Ostwald’s process
                      S Stearic acid               IV Haifa process


(A)     P-III, Q-I, R-IV, S-II


(B)     P-IV, Q-I, R-II, S-III


(C)     P-III, Q-IV, R-I, S-II


(D)     P-I, Q-IV, R-II, S-III


                                           Page 29
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GATE 2022 Chemical Engineering (CH)

Q.44    The directional derivative of f ( x, y, z )  4 x 2  2 y 2  z 2 at the point (1,1,1) in the
                                
        direction of the vector v  iˆ  kˆ is _________ (rounded off to two decimal places).




Q.45    Consider a sphere of radius 4, centered at the origin, with outward unit normal n̂
                                                                  2 xiˆ  3 yjˆ  4 zkˆ 
        on its surface S . The value of the surface integral                         nˆ dA is
                                                               S 
                                                                           4             
        ___________ (rounded off to one decimal place).




Q.46                   dy
        The equation        xy 2  2 y  x  4.5 with the initial condition y( x  0)  1 is to be
                       dx
        solved using a predictor-corrector approach. Use a predictor based on the implicit
        Euler’s method and a corrector based on the trapezoidal rule of integration, each
        with a full-step size of 0.5. Considering only positive values of y, the value of y at
        x = 0.5 is ___________ (rounded off to three decimal places).




                                             Page 30
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GATE 2022 Chemical Engineering (CH)

Q.47
        A substance at 4 °C has a thermal expansion coefficient β =               = 0 K-1, an
        isothermal compressibility, κ = −                   = 5 × 10−4 Pa-1 and a molar
        volume v = 18 × 10      m3 mol-1. If s is the molar entropy, then at 4 °C, the quantity
         v          evaluated for the substance is __________ J mol-1 K-1 (rounded off to
        the nearest integer).




Q.48    The molar excess Gibbs free energy (g ) of a liquid mixture of A and B is given by

                                 g
                                    = x x [C + C (x − x )]
                                 RT
        where x and x are the mole fraction of A and B, respectively, the universal gas
        constant, R = 8.314 J K-1 mol-1, T is the temperature in K, and C , C are
        temperature-dependent parameters. At 300 K, C = 0.45 and C = −0.018. If γ
        and γ are the activity coefficients of A and B, respectively, the value of

                                                   γ
                                              ln       dx
                                                   γ

        at 300 K and 1 bar is _________ (rounded off to the nearest integer).




                                         Page 31
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GATE 2022 Chemical Engineering (CH)
       For a pure substance, the following data at saturated conditions are given:
 Q.49
                              ln P (bar)                    T (K)

                                    0.693                         350
                                    1.386                         370

         Assume that the vapor phase behaves ideally, the molar volume of the liquid is
         negligible, and the latent heat of vaporization is constant over the given temperature
         range. The universal gas constant, R = 8.314 J K-1 mol-1. From the above data, the
         estimated latent heat of vaporization at 360 K is ____________ kJ/mol (rounded
         off to one decimal place).




 Q.50    Consider the process flowsheet in the figure. An irreversible liquid-phase reaction
         A → B (reaction rate −r = 164 x kmol m-3 h-1) occurs in a 1 m3 continuous stirred
         tank reactor (CSTR), where x is the mole fraction of A. A small amount of inert,
         I, is added to the reactor. The reactor effluent is separated in a perfect splitter to
         recover pure B product down the bottoms and a B-free distillate. A fraction of the
         distillate is purged and the rest is recycled back to the reactor. At a particular steady
         state, the product rate is 100 kmol h-1, the recycle rate is 200 kmol h-1 and the purge
         rate is 10 kmol h-1. Given the above information, the inert feed rate into the process
         is ____________ kmol h-1 (rounded off to two decimal places).




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GATE 2022 Chemical Engineering (CH)

Q.51    Two reservoirs located at the same altitude are connected by a straight horizontal
        pipe of length 120 m and inner diameter 0.5 m, as shown in the figure. A pump
        transfers the liquid of density 800 kg m-3 at a flow rate of 1 m3 s-1 from
        Reservoir-1 to Reservoir-2. The liquid levels in Reservoir-1 and Reservoir-2 are
        2 m and 10 m, respectively. Assume that the reservoirs’ cross-section areas are large
        enough to neglect the liquid velocity at the top of the reservoirs. All minor losses
        can be ignored. The acceleration due to gravity is 9.8 m s-2. If the friction factor for
        the pipe-flow is 0.01, the required power of the pump is _________ kW (rounded
        off to one decimal place).




Q.52    A venturi meter (venturi coefficient, C = 0.98) is connected to a pipe of inner
        diameter 50 mm. Water (density 1000 kg m-3) is flowing through the pipe. The
        pressure-drop measured across the venturi meter is 50 kPa. If the venturi throat
        diameter is 20 mm, the estimated flow rate of water is _______  10-3 m3 s-1
        (rounded off to two decimal places).




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Q.53    In a constant-rate cake filtration operation, the collected filtrate volumes are 120 m3
        and 240 m3 at 1 min and 2 min, respectively. Assume the cake resistance to be
        constant and the filter medium resistance to be negligible. If the pressure-drop
        across the cake is 10 kPa at 1 min, its value at 2 min is _________ kPa (rounded off
        to the nearest integer).




Q.54    A cylindrical fin of diameter 24 mm is attached horizontally to a vertical planar
        wall. The heat transfer rate from the fin to the surrounding air is 60% of the heat
        transfer rate if the entire fin were at the wall temperature. If the fin effectiveness is
        10, its length is ___________ mm (rounded off to the nearest integer).




Q.55    A single-effect evaporator with a heat transfer area of 70 m2 concentrates a salt
        solution using steam. The salt solution feed rate and temperature are 10000 kg h-1
        and 40 °C, respectively. The saturated steam feed rate and temperature are
        7500 kg h-1 and 150 °C, respectively. The boiling temperature of the solution in the
        evaporator is 80 °C. The average specific heat of the solution is 0.8 kcal kg-1 K-1.
        The latent heat of vaporization is 500 kcal kg-1. If the steam-economy is 0.8, the
        overall heat transfer coefficient is ________ kcal h-1 m-2 K-1 (rounded off to the
        nearest integer).




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Q.56    An equimolar binary mixture is to be separated in a simple tray-distillation column.
        The feed rate is 50 kmol min-1. The mole fractions of the more volatile component
        in the top and bottom products are 0.90 and 0.01, respectively. The feed as well as
        the reflux stream are saturated liquids. On application of the McCabe-Thiele
        method, the operating line for the stripping section is obtained as
                                       y = 1.5x − 0.005
        where y and x are the mole fractions of the more volatile component in the vapor
        and liquid phases, respectively. The reflux ratio is _______ (rounded off to two
        decimal places).




Q.57    The dry-bulb temperature of air in a room is 30 °C. The Antoine equation for water
        is given as
                                                        4000
                                      ln P sat  12.00 
                                                       T  40
                                                  sat
        where T is the temperature in K and P is the saturation vapor pressure in bar.
        The latent heat of vaporization of water is 2000 kJ kg-1, the humid heat is
        1.0 kJ kg-1 K-1, and the molecular weights of air and water are 28 kg kmol-1 and
        18 kg kmol-1, respectively. If the absolute humidity of air is Y′ kg moisture per kg
        dry air, then for a wet-bulb depression of 9 °C, 1000 × Y′ = _________________
        (rounded off to one decimal place).




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Q.58                                                                   K
        In the block diagram shown in the figure, the transfer function G   with
                                                                   ( s  1)
        K > 0 and τ > 0. The maximum value of K below which the system remains
        stable is __________ (rounded off to two decimal places).




Q.59    Consider the tank level control system shown in the figure, where the cross-section
        area of the tank is A. Assume perfect flow controllers (FC). The level controller
        (LC) is proportional-integral (PI). For an integral time, τ , the level controller gain,
        K , is tuned for critical damping. The value of          is ________ (rounded off to
        the nearest integer).




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GATE 2022 Chemical Engineering (CH)

Q.60 Consider a single-input-single-output (SISO) system with the transfer function

                                                     2(s  1)
                                    G p ( s) 
                                                 1      1    
                                                  s  1 s  1
                                                 2      4    

       where the time constants are in minutes. The system is forced by a unit step input at
       time t = 0. The time at which the output response reaches the maximum is
       __________ minutes (rounded off to two decimal places).




Q.61 Information for a proposed greenfield project is provided in the table. The discounted
     cash flow for the fourth year is Rs ________ crores (rounded off to one decimal
     place).


              Fixed capital investment (excluding land)          Rs 250 crores
                                            Salvage value        Rs 0
                     Yearly revenue from product sales           Rs 120 crores
                  Yearly manufacturing cost (excluding
                                                                 Rs 30 crores
                                         depreciation)
                                                 Interest rate   10% compounded annually
                                    Annual taxation rate         30%
                                                                 Double declining balance*
                                   Depreciation method
                                                                 over seven years
                                            Plant start-up       2 years after project initiation
                 2
          * dk = BVk−1 k: years post start-up          d: Depreciation amount BV: Book value
                 7




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Q.62     Consider the process in the figure. The liquid phase elementary reactions

                                A + B → P           −r    = k x x
                                P + B → S           −r    =k x x
                                S + A → 2P          −r    = k x x

         occur in the continuous stirred tank reactor (CSTR), where x is the mole fraction
         of the jth component (j = A, B, P, S) in the CSTR. It is given that k = k . All
         process feed, process exit and recycle streams are pure. At steady state, the net
         generation rate of the undesired product, S, in the CSTR is zero. As q = x /x
         is varied at constant reactor temperature, the reactor volume is adjusted to maintain
         a constant single-pass conversion of B. For a fixed product rate and 90%
         conversion of B in the reactor, the value of q that minimizes the sum of the molar
         flow rates of the A and S recycle streams is ________ (round off to one decimal
         place).




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Q.63     An elementary irreversible liquid-phase reaction, 2A → B, is carried out under
         isothermal conditions in a 1 m3 ideal plug flow reactor (PFR) as shown in the
         figure. The volumetric flow rate of fresh A, v = 10 m3 h-1, and its concentration
         C = 2 kmol m-3. For a recycle ratio R  0 , the conversion of A at location 2 with
         respect to the fresh feed (location 1) is 50%. For R   , the corresponding
         conversion of A is _________% (rounded off to one decimal place).




Q.64     An elementary irreversible gas-phase reaction, A → B + C, is carried out at fixed
         temperature and pressure in two separate ideal reactors: (i) a 10 m3 plug flow
         reactor (PFR), (ii) a 10 m3 continuous-stirred tank reactor (CSTR). If pure A is fed
         at 5 m3 h-1 to the PFR operating at 400 K, the conversion is 80%. If a mixture of
         50 mol% of A and 50 mol% of an inert is fed at 5 m3 h-1 to the CSTR operating at
         425 K, the conversion is 80%. The universal gas constant R = 8.314 J mol-1 K-1.
         Assuming the Arrhenius rate law, the estimated activation energy is
         __________kJ mol-1 (rounded off to one decimal place).




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Q.65     An elementary irreversible liquid-phase reaction, 2P ⎯ Q, where the rate
         constant k = 2 L mol-1 min-1, takes place in an isothermal non-ideal reactor. The
         E-curve in a tracer experiment is shown in the figure. Pure P (2 mol L-1) is fed to
         the reactor. Using the segregated model, the percentage conversion of P at the exit
         of the reactor is __________% (rounded off to the nearest integer).




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Q. No.   Session Question   Subject   Key/Range        Mark
                 Type       Name                       (MK)
1        4       MCQ        GA        C                1
2        4       MCQ        GA        D                1
3        4       MCQ        GA        C                1
4        4       MCQ        GA        C                1
5        4       MCQ        GA        C                1
6        4       MCQ        GA        B                2
7        4       MCQ        GA        D                2
8        4       MCQ        GA        A                2
9        4       MCQ        GA        C                2
10       4       MCQ        GA        C                2
11       4       MCQ        CH        D                1
12       4       MCQ        CH        B                1
13       4       MCQ        CH        C                1
14       4       MCQ        CH        A                1
15       4       MCQ        CH        D                1
16       4       MCQ        CH        A                1
17       4       MCQ        CH        A                1
18       4       MCQ        CH        A                1
19       4       MCQ        CH        D                1
20       4       MCQ        CH        A                1
21       4       MCQ        CH        C                1
22       4       MCQ        CH        C                1
23       4       MCQ        CH        A                1
24       4       MCQ        CH        B                1
25       4       MCQ        CH        C                1
26       4       MCQ        CH        C                1
27       4       MCQ        CH        A                1
28       4       NAT        CH        2.830 to 2.850   1
29       4       NAT        CH        178.7 to 180.7   1
30       4       NAT        CH        0.14 to 0.15     1
31       4       NAT        CH        53.0 to 54.0     1
32       4       NAT        CH        221.0 to 223.0   1
33       4       NAT        CH        8.0 to 8.4       1
34       4       NAT        CH        2 to 2           1
35       4       NAT        CH        24.7 to 25.1     1
36       4       MCQ        CH        A                2
37       4       MCQ        CH        A                2
38       4       MCQ        CH        A                2
39       4       MCQ        CH        B                2
40       4       MCQ        CH        A                2
41       4       MCQ        CH        A                2
42       4       MCQ        CH        B                2
43       4       MCQ        CH        C                2
44       4       NAT        CH        4.20 to 4.30     2
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45   4   NAT   CH   191.9 to 192.1                   2
46   4   NAT   CH   0.860 to 0.880                   2
47   4   NAT   CH   0 to 0                           2
48   4   NAT   CH   0 to 0                           2
49   4   NAT   CH   36.3 to 38.3                     2
50   4   NAT   CH   0.95 to 1.05                     2
51   4   NAT   CH   87.0 to 88.0 OR 161.7 to 163.2   2
52   4   NAT   CH   3.10 to 3.17                     2
53   4   NAT   CH   20 to 20                         2
54   4   NAT   CH   94 to 94                         2
55   4   NAT   CH   675 to 680                       2
56   4   NAT   CH   0.61 to 0.65                     2
57   4   NAT   CH   10.0 to 12.0                     2
58   4   NAT   CH   0.70 to 0.72                     2
59   4   NAT   CH   -4 to -4 OR 4 to 4               2
60   4   NAT   CH   0.54 to 0.56                     2
61   4   NAT   CH   52.0 to 54.0                     2
62   4   NAT   CH   3 to 3                           2
63   4   NAT   CH   38.0 to 38.5                     2
64   4   NAT   CH   47.0 to 49.0                     2
65   4   NAT   CH   50 to 50                         2
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Source: GATE. Question paper published by GATE.