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GATE CH 2024: Chemical Engineering

  • Date: 4 February 2024
  • Paper code: CH
  • Language: English
  • 38 pages
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Chemical Engineering (CH)


General Aptitude (GA)
Q.1 – Q.5 Carry ONE mark Each

 Q.1       If ‘→’ denotes increasing order of intensity, then the meaning of the words

           [simmer → seethe → smolder] is analogous to [break → raze → ________ ].

           Which one of the given options is appropriate to fill the blank?




 (A)       obfuscate


 (B)       obliterate


 (C)       fracture


 (D)       fissure




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Chemical Engineering (CH)



 Q.2       In a locality, the houses are numbered in the following way:

           The house-numbers on one side of a road are consecutive odd integers starting from
           301, while the house-numbers on the other side of the road are consecutive even
           numbers starting from 302. The total number of houses is the same on both sides of
           the road.

           If the difference of the sum of the house-numbers between the two sides of the road
           is 27, then the number of houses on each side of the road is




 (A)       27


 (B)       52


 (C)       54


 (D)       26




 Q.3                                                        p       p
                                              p        p q   ( −1)
           For positive integers p and q , with ≠ 1 , ( ) = p q    . Then,
                                               q       q




 (A)       q p = pq

 (B)       qp = p2q

 (C)       √q = √p

           p       q
 (D)       √q = √p




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Chemical Engineering (CH)



 Q.4       Which one of the given options is a possible value of x in the following sequence?

                                       3, 7, 15, x, 63, 127, 255




 (A)       35


 (B)       40


 (C)       45


 (D)       31




 Q.5       On a given day, how many times will the second-hand and the minute-hand of a
           clock cross each other during the clock time 12:05:00 hours to 12:55:00 hours?




 (A)       51


 (B)       49


 (C)       50


 (D)       55




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Chemical Engineering (CH)


Q.6 – Q.10 Carry TWO marks Each

 Q.6       In the given text, the blanks are numbered (i)−(iv). Select the best match for
           all the blanks.

           From the ancient Athenian arena to the modern Olympic stadiums,
                         (i)                                                       (ii)
           athletics             the potential for a spectacle. The crowd                  with bated
           breath as the Olympian artist twists his body, stretching the javelin behind him.
                                                                              (iii)
           Twelve strides in, he begins to cross-step. Six cross-steps                    in an abrupt
                                                     (iv)
           stop on his left foot. As his body                 like a door turning on a hinge, the
           javelin is launched skyward at a precise angle.




 (A)        (i) hold            (ii) waits         (iii) culminates   (iv) pivot


 (B)        (i) holds           (ii) wait          (iii) culminates   (iv) pivot


 (C)        (i) hold            (ii) wait          (iii) culminate    (iv) pivots


 (D)        (i) holds           (ii) waits         (iii) culminate    (iv) pivots




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Chemical Engineering (CH)



 Q.7       Three distinct sets of indistinguishable twins are to be seated at a circular table that
           has 8 identical chairs. Unique seating arrangements are defined by the relative
           positions of the people.

           How many unique seating arrangements are possible such that each person is sitting
           next to their twin?




 (A)       12


 (B)       14


 (C)       10


 (D)       28




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Chemical Engineering (CH)



 Q.8       The chart given below compares the Installed Capacity (MW) of four power
           generation technologies, T1, T2, T3, and T4, and their Electricity Generation
           (MWh) in a time of 1000 hours (h).


                                                              Installed Capacity          Electricity Generation
                                               14000                                                                70
                                               13000                                                                65
                                               12000                                                                60




                Electricity Generation (MWh)
                                               11000                                                                55




                                                                                                                         Installed Capacity (MW)
                                               10000                                                                50
                                                9000                                                                45
                                                8000                                                                40
                                                7000                                                                35
                                                6000                                                                30
                                                5000                                                                25
                                                4000                                                                20
                                                3000                                                                15
                                                2000                                                                10
                                                1000                                                                5
                                                   0                                                                0
                                                             T1              T2               T3               T4
                                                                       Power Generation Technology


           The Capacity Factor of a power generation technology is:

                                                                               Electricity Generation (MWh)
                                                       Capacity Factor =
                                                                           Installed Capacity (MW) × 1000 (h)

           Which one of the given technologies has the highest Capacity Factor?




 (A)       T1



 (B)       T2



 (C)       T3



 (D)       T4




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Chemical Engineering (CH)



 Q.9       In the 4 × 4 array shown below, each cell of the first three columns has either a
           cross (X) or a number, as per the given rule.




           Rule: The number in a cell represents the count of crosses around its immediate
           neighboring cells (left, right, top, bottom, diagonals).

           As per this rule, the maximum number of crosses possible in the empty column is




 (A)       0


 (B)       1


 (C)       2


 (D)       3




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Chemical Engineering (CH)



 Q.10      During a half-moon phase, the Earth-Moon-Sun form a right triangle. If the
           Moon-Earth-Sun angle at this half-moon phase is measured to be 89.85°, the ratio
           of the Earth-Sun and Earth-Moon distances is closest to




 (A)       328


 (B)       382


 (C)       238


 (D)       283




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Chemical Engineering (CH)


Q.11 – Q.35 Carry ONE mark Each

 Q.11      The first non-zero term in the Taylor series expansion of (1 − x) − e −x
           about x = 0 is




 (A)       1


 (B)       −1


 (C)       x2
           2

 (D)         x2
           −
             2




 Q.12      Consider the normal probability distribution function

                                                  4              2
                                        f(x) =           e −8(x+3)
                                                 √2π
           If μ and σ are the mean and standard deviation of f(x) respectively, then the
           ordered pair (μ, σ) is




 (A)            1
           (3, 4)


 (B)                1
           (−3, 4)


 (C)       (3, 4)

 (D)       (−3, 4)



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Chemical Engineering (CH)



 Q.13      If z1 = −1 + i and z2 = 2i, where i = √−1, then Arg(z1 ⁄z2 ) is




 (A)       3π
            4

 (B)       π
           4

 (C)       π
           2

 (D)       π
           3




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Chemical Engineering (CH)



 Q.14      A homogeneous azeotropic distillation process separates an azeotropic AB binary
           feed using a heavy entrainer, E, as shown in the figure. The loss of E in the two
           product streams is negligible so that E circulates around the process in a closed-
           circuit. For a distillation column with fully specified feed(s), given operating
           pressure, a single distillate stream and a single bottoms stream, the steady-state
           degrees of freedom equals 2. For the process in the figure with a fully specified AB
           feed stream and given column operating pressures, the steady-state degrees of
           freedom equals




 (A)       3


 (B)       4


 (C)       5


 (D)       6




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Chemical Engineering (CH)



 Q.15      An infinitely long cylindrical water filament of radius R is surrounded by air.
           Assume water and air to be static. The pressure outside the filament is Pout and the
           pressure inside is Pin . If γ is the surface tension of the water-air interface, then
           Pin − Pout is




           2γ
 (A)       R


 (B)       0


 (C)       γ
           R

 (D)       4γ
           R




 Q.16                                                                           ̂ , where î, ĵ and
           The velocity field in an incompressible flow is v = αxyî + vy ĵ + βk
           ̂ are unit-vectors in the (x, y, z) Cartesian coordinate system. Given that α and β
           k
           are constants, and vy = 0 at y = 0, the correct expression for vy is




 (A)       −αxy
            2


 (B)       −αy 2
            2

 (C)       αy 2
            2

 (D)       αxy
            2




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 Q.17      Consider the steady, uni-directional diffusion of a binary mixture of A and B across
           a vertical slab of dimensions 0.2 m × 0.1 m × 0.02 m as shown in the figure. The
           total molar concentration of A and B is constant at 100 mol m−3 . The mole fraction
           of A on the left and right faces of the slab are maintained at 0.8 and 0.2, respectively.
           If the binary diffusion coefficient DAB = 1 × 10−5 m2 s−1 , the molar flow rate of A
           in mol s−1 , along the horizontal x direction is




 (A)       6 × 10−4


 (B)       6 × 10−6


 (C)       3 × 10−6


 (D)       3 × 10−4




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 Q.18      Consider a vapour-liquid mixture of components A and B that obeys Raoult’s law.
           The vapour pressure of A is half that of B. The vapour phase concentrations of A
           and B are 3 mol m−3 and 6 mol m−3, respectively. At equilibrium, the ratio of the
           liquid phase concentration of A to that of B is




 (A)       1.0


 (B)       0.5


 (C)       2.0


 (D)       1.5




 Q.19      The ratio of the activation energy of a chemical reaction to the universal gas constant
           is 1000 K. The temperature-dependence of the reaction rate constant follows the
           collision theory. The ratio of the rate constant at 600 K to that at 400 K is




 (A)       2.818


 (B)       4.323


 (C)       1.502


 (D)       1.000




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Chemical Engineering (CH)




 Q.20      The rate of a reaction A → B is 0.2 mol m−3 s −1 at a particular concentration CA1 .
           The rate constant of the reaction at a given temperature is 0.1 m3 mol−1 s −1 . If the
           reactant concentration is increased to 10 CA1 at the same temperature, the reaction
           rate, in mol m−3 s−1 , is




 (A)       20


 (B)       10


 (C)       100


 (D)       50




 Q.21                                                        k1         k2
           Two parallel first-order liquid phase reactions A → B and A → C are carried out in a
           well-mixed isothermal batch reactor. The initial concentration of A in the reactor is
           1 kmol m−3 , while that of B and C is zero. After 2 hours, the concentration of A
           reduces to half its initial value, and the concentration of B is twice that of C. The
           rate constants k1 and k2 , in h−1 , are, respectively




 (A)       0.40, 0.20


 (B)       0.23, 0.12


 (C)       0.50, 0.25


 (D)       0.36, 0.18




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Chemical Engineering (CH)



 Q.22      Consider the block diagram in the figure with control input u, disturbance d and
           output y. For the feedforward controller, the ordered pair (K, α⁄β ) is




 (A)       (0.5, 2)


 (B)       (−0.5, 0.5)


 (C)       (−2, 2)


 (D)       (2, 0.5)




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Chemical Engineering (CH)



 Q.23      Consider the control structure for the overhead section of a distillation column
           shown in the figure. The composition controller (CC) controls the heavy key
           impurity in the distillate by adjusting the setpoint of the reflux flow controller in a
           cascade arrangement. The sign of the controller gain for the pressure controller (PC)
           and that for the composition controller (CC) are, respectively,




 (A)       negative, negative


 (B)       negative, positive


 (C)       positive, positive


 (D)       positive, negative




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Chemical Engineering (CH)



 Q.24      Which one of the given statements is correct with reference to gas-liquid contactors
           for mass transfer applications?




 (A)       A tray tower is more suitable for foaming systems than a packed tower.


 (B)       Tray towers are preferred over packed towers for systems requiring frequent
           cleaning.


 (C)       For a given liquid flow rate, the gas flow rate in the loading region is greater than
           that in the flooding region.


 (D)       Flooding can never occur for counter-current contact.




 Q.25      In an ammonia manufacturing facility, the necessary hydrogen is generated from
           methane. The facility consists of the following process units -

           P: Methanator, Q: CO shift convertor, R: CO2 stripper, S: Reformer, T: Ammonia
           convertor

           The correct order of these units, starting from methane feed is




 (A)       S, Q, R, P, T


 (B)       P, Q, R, S, T


 (C)       S, P, Q, R, T


 (D)       P, S, T, Q, R




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Chemical Engineering (CH)



 Q.26      Consider a linear homogeneous system of equations Ax = 0, where A is an n × n
           matrix, x is an n × 1 vector and 0 is an n × 1 null vector. Let r be the rank of A. For
           a non-trivial solution to exist, which of the following conditions is/are satisfied?




 (A)       Determinant of A = 0


 (B)       r=n


 (C)       r<n


 (D)       Determinant of A ≠ 0




 Q.27      If the Prandtl number Pr = 0.01, which of the following statements is/are correct?




 (A)       The momentum diffusivity is much larger than the thermal diffusivity.


 (B)       The thickness of the momentum boundary layer is much smaller than that of the
           thermal boundary layer.


 (C)       The thickness of the momentum boundary layer is much larger than that of the
           thermal boundary layer.


 (D)       The momentum diffusivity is much smaller than the thermal diffusivity.




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 Q.28      For the electrolytic cell in a chlor-alkali plant, which of the following statements
           is/are correct?




 (A)       A membrane cell operates at a higher brine concentration than a diaphragm cell.


 (B)       Chlorine gas is produced at the cathode.


 (C)       Hydrogen gas is produced at the cathode.


 (D)       The caustic product stream exits the cathode compartment.




 Q.29      Which of the following statements with reference to the petroleum/petrochemical
           industry is/are correct?




 (A)       Catalytic hydrocracking converts heavier hydrocarbons to lighter hydrocarbons.


 (B)       Catalytic reforming converts straight-chain hydrocarbons to aromatics.


 (C)       Cumene is manufactured by the catalytic alkylation of benzene with propylene.


 (D)       Vinyl acetate is manufactured by reacting methane with acetic acid over a palladium
           catalyst.




                                         Page 20 of 38
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Chemical Engineering (CH)



 Q.30                             −5 a
           Consider a matrix A = [          ], where a is a constant. If the eigenvalues of A are
                                  −2 −2
           −1 and −6, then the value of a, rounded off to the nearest integer, is ____________




 Q.31      Consider the reaction N2 (g) + 3H2 (g) ⇌ 2NH3 (g) in a continuous flow reactor
           under steady-state conditions. The component flow rates at the reactor inlet are
                                                         0
           FN02 = 100 mol s −1 , FH02 = 300 mol s −1 , Finert = 1 mol s−1 . If the fractional
           conversion of H2 is 0.60, the outlet flow rate of N2 , in mol s −1 , rounded off to the
           nearest integer, is _________




 Q.32      Consider a binary mixture of components A and B at temperature T and pressure P.
           Let V̅A and V̅B be the partial molar volumes of A and B, respectively. At a certain
           mole fraction of A, xA

                         ∂V̅A                       ∂V̅B
                     (        ) = 22 cm3 mol−1 and (     ) = −18 cm3 mol−1
                         ∂xA T,P                     ∂xA T,P


           The value of xA , rounded off to 2 decimal places, is ________




 Q.33      Consider the steady, uni-directional, fully-developed, pressure-driven laminar flow
           of an incompressible Newtonian fluid through a circular pipe of inner radius 5.0 cm.
           The magnitude of shear stress at the inner wall of the pipe is 0.1 N m−2. At a radial
           distance of 1.0 cm from the pipe axis, the magnitude of the shear stress, in N m−2 ,
           rounded off to 3 decimal places, is ______




 Q.34      The opposite faces of a metal slab of thickness 5 cm and thermal conductivity
           400 W m−1 ℃−1 are maintained at 500 ℃ and 200 ℃. The area of each face is
           0.02 m2 . Assume that the heat transfer is steady and occurs only in the direction
           perpendicular to the faces. The magnitude of the heat transfer rate, in kW, rounded
           off to the nearest integer, is _______




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 Q.35      The capital cost of a distillation column is Rs. 90 lakhs. The cost is to be fully
           depreciated (salvage value is zero) using the double-declining balance method over
           10 years. At the end of two years of continuous operation, the book-value of the
           column, in lakhs of rupees, rounded off to 1 decimal place, is _______




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Q.36 – Q.65 Carry TWO marks Each

 Q.36      Consider a steady, fully-developed, uni-directional laminar flow of an
           incompressible Newtonian fluid (viscosity μ) between two infinitely long
           horizontal plates separated by a distance 2H as shown in the figure. The flow is
           driven by the combined action of a pressure gradient and the motion of the bottom
                                                                   ∆P   (P −P )
           plate at y = −H in the negative x direction. Given that L = 1 L 2 > 0, where P1
           and P2 are the pressures at two x locations separated by a distance L. The bottom
           plate has a velocity of magnitude V with respect to the stationary top plate at
           y = H. Which one of the following represents the x-component of the fluid velocity
           vector?




 (A)                                   ∆P H 2     y2    V y
                                              (1 − 2 ) + ( − 1)
                                        L 2μ      H     2 H


 (B)                                   ∆P H 2 y 2      V y
                                             ( 2 − 1) + ( − 1)
                                        L 2μ H         2 H


 (C)                                   ∆P H 2 y 2      V y
                                             ( 2 − 1) − ( − 1)
                                        L 2μ H         2 H


 (D)                                   ∆P H 2     y2    V y
                                              (1 − 2 ) − ( − 1)
                                        L 2μ      H     2 H




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 Q.37      The temperatures of two large parallel plates of equal emissivity are 900 K and
           300 K. A reflection radiation shield of low emissivity and negligible conductive
           resistance is placed parallelly between them. The steady-state temperature of the
           shield, in K, is




 (A)       759


 (B)       559


 (C)       659


 (D)       859




 Q.38      Hot oil at 110 ℃ heats water from 30 ℃ to 70 ℃ in a counter-current double-pipe
           heat exchanger. The flow rates of water and oil are 50 kg min−1 and 100 kg min−1,
           respectively and their specific heat capacities are 4.2 kJ kg −1 ℃−1 and
           2.0 kJ kg −1 ℃−1 , respectively. Assume the heat exchanger is at steady state. If the
           overall heat transfer coefficient is 200 W m−2 ℃−1 , the heat transfer area in m2 is




 (A)       17.9


 (B)       1.1


 (C)       5.2


 (D)       35.2




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 Q. 39     A solid slab of thickness H1 is initially at a uniform temperature T0 . At time t = 0,
           the temperature of the top surface at y = H1 is increased to T1 , while the bottom
           surface at y = 0 is maintained at T0 for t ≥ 0. Assume heat transfer occurs only in
           the y-direction, and all thermal properties of the slab are constant. The time required
           for the temperature at y = H1 /2 to reach 99% of its final steady value is τ1 . If the
           thickness of the slab is doubled to H2 = 2 H1 , and the time required for the
           temperature at y = H2 /2 to reach 99% of its final steady value is τ2 , then τ2 ⁄τ1 is




 (A)       2


 (B)       1
           4

 (C)       4


 (D)       1
           2




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 Q.40      A gas stream containing 95 mol% CO2 and 5 mol% ethanol is to be scrubbed with
           pure water in a counter-current, isothermal absorption column to remove ethanol.
           The desired composition of ethanol in the exit gas stream is 0.5 mol%. The
           equilibrium mole fraction of ethanol in the gas phase, y ∗ , is related to that in the
           liquid phase, x, as y ∗ = 2x. Assume CO2 is insoluble in water and neglect
           evaporation of water. If the water flow rate is twice the minimum, the mole fraction
           of ethanol in the spent water is




 (A)       0.0225


 (B)       0.0126


 (C)       0.0428


 (D)       0.0316




 Q.41      Sulfur dioxide (SO2) gas diffuses through a stagnant air-film of thickness 2 mm at
           1 bar and 30 ℃. The diffusion coefficient of SO2 in air is 1 × 10−5 m2 s −1 . The SO2
           partial pressures at the opposite sides of the film are 0.15 bar and 0.05 bar. The
           universal gas constant is 8.314 J mol−1 K −1. Assuming ideal gas behavior, the
           steady-state flux of SO2 in mol m−2 s−1 through the air-film is




 (A)       0.077


 (B)       0.022


 (C)       0.085


 (D)       0.057




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 Q.42      A simple distillation column separates a binary mixture of A and B. The relative
           volatility of A with respect to B is 2. The steady-state composition of A in the vapour
           leaving the 1st, 2nd and 3rd trays in the rectifying section are 94, 90 and 85 mol%,
           respectively. For ideal trays and constant molal overflow, the reflux-to-distillate
           ratio is




 (A)       1.9


 (B)       2.7


 (C)       1.2


 (D)       1.1




 Q.43      Alumina particles with an initial moisture content of 5 kg per kg dry solid are dried
           in a batch dryer. For the first two hours, the measured drying rate is constant at
           2 kg m−2 h−1 . Thereafter, in the falling-rate period, the rate decreases linearly with
           the moisture content. The equilibrium moisture content is 0.05 kg per kg dry solid
           and the drying area of the particles is 0.5 m2 per kg dry solid. The total drying
           time, in h, to reduce the moisture content to half its initial value is




 (A)       4.13


 (B)       2.55


 (C)       3.22


 (D)       5.13




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 Q.44      A first-order heterogenous reaction A → B is carried out using a porous spherical
           catalyst. Assume isothermal conditions, and that intraphase diffusion controls the
           reaction rate. At a bulk A concentration of 0.3 mol L−1 , the observed reaction rate
           in a 3 mm diameter catalyst particle is 0.2 mol s−1 L−1 catalyst volume. At a bulk
           A concentration of 0.1 mol L−1 , the observed reaction rate, in mol s −1 L−1 catalyst
           volume, in a 6 mm diameter catalyst particle, is




 (A)       0.011


 (B)       0.033


 (C)       0.022


 (D)       0.005




 Q.45      A first-order liquid phase reaction A → B is carried out in two isothermal plug
           flow reactors (PFRs) of volume 1 m3 each, connected in series. The feed flow rate
           and concentration of A to the first reactor are 10 m3 h−1 and 1 kmol m−3 ,
           respectively. At steady-state, the concentration of A at the exit of the second reactor
           is 0.2 kmol m−3 . If the two PFRs are replaced by two equal-volume continuously
           stirred tank reactors (CSTRs) to achieve the same overall steady-state conversion,
           the volume of each CSTR, in m3 , is




 (A)       1.54


 (B)       3.84


 (C)       7.28


 (D)       1.98




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Chemical Engineering (CH)



 Q.46      The residence time distribution, E, for a non-ideal flow reactor is given in the figure.
           A first-order liquid phase reaction with a rate constant 0.2 min−1 is carried out in
           the reactor. For an inlet reactant concentration of 2 mol L−1 , the reactant
           concentration (in mol L−1) in the exit stream is




 (A)       0.905


 (B)       0.452


 (C)       1.902


 (D)       0.502




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Chemical Engineering (CH)



 Q.47      Let r and θ be the polar coordinates defined by x = r cos θ and y = r sin θ.
           The area of the cardioid r = a (1 − cos θ), 0 ≤ θ ≤ 2π, is




 (A)       3πa2
            2

 (B)       2πa2
            3

 (C)       3πa2


 (D)       2πa2




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 Q.48      For the block diagram shown in the figure, the correct expression for the transfer
                         y1 (s)
           function Gd = d(s)   is




 (A)                                              −Gp1 Gc2
                                       (1 + Gc1 Gc2 Gp1 )(1 + Gc2 Gp2 )


 (B)                                             −Gp1 Gc2
                                       1 + Gc2 Gp2 + Gc1 Gc2 Gp1 Gp2


 (C)                                             −Gp1 Gc2
                                         1 + Gc2 Gp2 + Gc1 Gc2 Gp1


 (D)                                                1
                                       1 + Gc2 Gp2 + Gc1 Gc2 Gp1 Gp2




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 Q.49      For purchasing a batch reactor, three alternatives P, Q and R have emerged, as
           summarized in the table. For a compound interest rate of 10% per annum, choose
           the correct option that arranges the alternatives, in order, from the least expensive
           to the most expensive.


                                                              P     Q       R

                                       Installed Cost
                                                              15   25      35
                                       (lakh rupees)

                                   Equipment Life
                                                              3     5       7
                                       (years)

                                 Maintenance Cost
                                                              4     3       2
                               (lakh rupees per year)




 (A)       P, Q, R


 (B)       R, P, Q


 (C)       R, Q, P


 (D)       Q, R, P




 Q.50     The Newton-Raphson method is used to solve f(x) = 0, where f(x) = e x − 5x.

          If the initial guess x (0) = 1.0, the value of the next iterate, x (1) , rounded off to 2
          decimal places, is ______




 Q.51                                                                           ̂ , where î, ĵ and
          Consider the line integral ∫C F(r) ⋅ dr , with F(r) = x î + y ĵ + z k
          ̂
          k are unit vectors in the (x, y, z) Cartesian coordinate system. The path C is given
          by r(t) = cos(t) î + sin(t) ĵ + t ̂k, where 0 ≤ t ≤ π. The value of the integral,
          rounded off to 2 decimal places, is _________



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 Q.52                                                          d2 y       dy
          Consider the ordinary differential equation x 2 dx 2 − x dx − 3y = 0, with the
          boundary conditions y(x = 1) = 2 and y(x = 2) = 17⁄2. The solution y(x) at
          x = 3⁄2 , rounded off to 2 decimal places, is ___________




 Q.53     Consider the function f(x, y, z) = x 4 + 2 y 3 + z 2 . The directional derivative of the
          function at the point P (−1, 1, −1) along (î + ĵ), where î and ĵ are unit vectors in
          the x and y directions, respectively, rounded off to 2 decimal places, is _______


 Q.54     Consider the process in the figure for manufacturing B. The feed to the process is
          90 mol% A and a close-boiling inert component I. At a particular steady-state:

                      •   B product rate is 100 kmol h−1
                      •   Single-pass conversion of A in the reactor is 50%
                      •   Recycle-to-purge stream flow ratio is 10

          The flow rate of A in the purge stream in kmol h−1 , rounded off to 1 decimal place,
          is _____




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 Q.55     Methane combusts with air in a furnace as CH4 + 2O2 → CO2 + 2H2 O. The heat
          of reaction ΔHrxn = −880 kJ per mol CH4 and is assumed to be constant. The
          furnace is well-insulated and no other side reactions occur. All components behave
          as ideal gases with a constant molar heat capacity of 44 J mol−1 ℃−1 . Air may be
          considered as 20 mol% O2 and 80 mol% N2 . The air-fuel mixture enters the furnace
          at 50 °C. The methane conversion X varies with the air-to-methane mole ratio, r, as

                           X = 1 − 0.1 e −2(r−rs )   with   0.9 rs ≤ r ≤ 1.1 rs

          where rs is the stoichiometric air-to-methane mole ratio. For r = 1.05 rs , the exit
          flue gas temperature in ℃, rounded off to 1 decimal place, is ______




 Q.56     An isolated system consists of two perfectly sealed cuboidal compartments A and
          B separated by a movable rigid wall of cross-sectional area 0.1 m2 as shown in the
          figure. Initially, the movable wall is held in place by latches L1 and L2 such that the
          volume of compartment A is 0.1 m3 . Compartment A contains a monoatomic ideal
          gas at 5 bar and 400 K. Compartment B is perfectly evacuated and contains a
          massless Hookean spring of force constant 0.3 N m−1 at its equilibrium length
          (stored elastic energy is zero). The latches L1 and L2 are released, the wall moves
          to the right by 0.2 m, where it is held at the new position by latches L3 and L4 .
          Assume all the walls and latches are massless. The final equilibrium temperature, in
          K, of the gas in compartment A, rounded off to 1 decimal place, is _________




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 Q.57     Ethylene obeys the truncated virial equation-of-state

                                             PV     BP
                                                =1+
                                             RT     RT


          where P is the pressure, V is the molar volume, T is the absolute temperature and B
          is the second virial coefficient.                The universal gas constant
                              3    −1 −1
          R = 83.14 bar cm mol K . At 340 K, the slope of the compressibility factor
          vs. pressure curve is −3.538 × 10−3 bar −1 . Let G R denote the molar residual Gibbs
                                                           ∂G R
          free energy. At these conditions, the value of ( ∂P ) , in cm3 mol−1 , rounded off
                                                                  T
          to 1 decimal place, is ___________




 Q.58     A metallic spherical particle of density 7001 kg m−3 and diameter 1 mm is settling
          steadily due to gravity in a stagnant gas of density 1 kg m−3 and viscosity
          10−5 kg m−1 s −1. Take g = 9.8 m s−2 . Assume that the settling occurs in the
          regime where the drag coefficient CD is independent of the Reynolds number, and
          equals 0.44. The terminal settling velocity of the particle, in m s−1 , rounded off to
          2 decimal places, is ____




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 Q.59     Water of density 1000 kg m−3 is pumped at a volumetric flow rate of
          3.14 × 10−2 m3 s −1 , through a pipe of inner diameter 10 cm and length 100 m, from
          a large Reservoir 1 to another large Reservoir 2 at a height 50 m above Reservoir 1,
          as shown in the figure. The flow in the pipe is in the turbulent regime with a Darcy
          friction factor f = 0.06, and a kinetic energy correction factor α = 1. Take g =
          9.8 m s −2. If all minor losses are negligible, and the pump efficiency is 100%, the
          pump power, in kW, rounded off to 2 decimal places, is ______




 Q.60     A Venturi meter with a throat diameter d = 2 cm measures the flow rate in a pipe of
          diameter D = 6 cm, as shown in the figure. A U-tube manometer is connected to
          measure the pressure drop. Assume the discharge coefficient is independent of the
          Reynolds number and geometric ratios. If the volumetric flow rate through the pipe
          is doubled Q2 = 2Q1 , the corresponding ratio of the manometer readings ∆ℎ2 ⁄∆ℎ1,
          rounded off to the nearest integer, is _______




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 Q.61     Heat is available at a rate of 2 kW from a thermal reservoir at 400 K. A two-stage
          process harnesses this heat to produce power. Stages 1 and 2 reject heat at 360 K
          and 300 K, respectively. Stage 2 is driven by the heat rejected by Stage 1. If the
          overall process efficiency is 50% of the corresponding Carnot efficiency, the power
          delivered by the process, in kW, rounded off to 2 decimal places, is ______




 Q.62     A chemostat with cell recycle is shown in the figure. The feed flow rate and culture
          volume are F = 75 L h−1 and V = 200 L, respectively. The glucose concentration in
          the feed CS0 = 15 g L−1 . Assume Monod kinetics with specific cell growth rate
                1 dC     μ C
          μg = C dtC = K m+CS ,     where     μm = 0.25 h−1 and Ks = 1 g L−1.         Assume
                  C          S   S
          maintenance and death rates to be zero, input feed to be sterile (CC0 = 0) and steady-
          state operation. The glucose concentration in the recycle stream, CS1 , in g L−1 ,
          rounded off to 1 decimal place, is _________




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 Q.63     Consider the surge drum in the figure. Initially the system is at steady-state with a
          hold-up V̅ = 5 m3, which is 50% of full tank capacity, Vfull , and volumetric flow
          rates F̅in = F̅out = 1 m3 h−1. The high hold-up alarm limit Vℎigℎ = 0.8 Vfull while
          the low hold-up alarm limit Vlow = 0.2 Vfull . A proportional (P-only) controller
          manipulates the outflow to regulate the hold-up V as Fout = Kc (V − V̅ ) + F̅out . At
          t = 0, Fin increases as a step from 1 m3 h−1 to 2 m3 h−1. Assume linear control
          valves and instantaneous valve dynamics. Let Kcmin be the minimum controller gain
          that ensures V never exceeds Vℎigℎ . The value of Kcmin , in ℎ−1 , rounded off to 2
          decimal places, is _________




 Q. 64    A PD controller with transfer function Gc is used to stabilize an open-loop unstable
          process with transfer function Gp , where

                                       τD s + 1                 1
                             Gc = Kc τ           , Gp =
                                        D
                                      (20 )s + 1        (s − 1)(10s + 1)
          and time is in minutes. From the necessary conditions for closed-loop stability, the
          maximum feasible value of τD , in minutes, rounded off to 1 decimal place, is
          ____________



 Q.65     Consider a tray-column of diameter 120 cm. Each downcomer has a cross-sectional
          area of 575 cm2. For a tray, the percentage column cross-sectional area not available
          for vapour flow due to the downcomers, rounded off to 1 decimal place, is
          _____________



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Source: GATE. Question paper published by GATE.