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MP SET 2024: State Eligibility Test, Chemical Sciences

  • Language: Bilingual
  • 36 pages
MP SET 2024 question paper, State Eligibility Test 2024, Chemical Sciences, page 1 of 36
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R/P/P/2024/II                                              Question Booklet No.


                                     Subject-CHEMjCAL SCIENCES
 SET            A                         ■f§[tfhT       )
                                                                                             240209493
                                                Paper J! (Optional)
                                                          cpl^-02

  Name                                           Subject-Code.-02
                                                           ■ uttsndl 3WIT 3ipiirfgi ^        if
                                                   .        Caodidate should write his/her
  Roll No.                                                  Roll No. Id the glyeo boxes.

  ■gfStT          "W^/Nc. ofPrinted Pages : 32                                             TP^/Total No. of Questions : 100
           :3                                      ^         ^                                    ^"ifeh/Maximiim Marks : 200
  Time Allowed: 3 Hours to complete bothJst and Ilnd question paper


                                  iTTc^TRT^giaHt^ft'^TiTR^t 1       R<c*iW ^            (afr.T^anr,                                ^
                  ^       "^eT *qTse itt ^            I                                                                           |
      ^         W^            f twIRR ^ fileil<b< 150   Tra>R ^ f ^rat TIc^ TRT 2 ^ ^ t I                                         R#
      Wi stPtanf f                           2 3^1^outfit i dt^xTfofwr^lcT^aitf                      i                       uw>iiH
        11                                              „          ".                                                    •    !
                   I                     .                                                 (IRT^fQEir 1-50)
            iRT-^u        ^      ^   afttfrtsft ^ ^tjpRT "feBa air                         (117^^^31151-150)
      OT RTa-^feraif ^          itw atTartr ^ ar asrff if 11attp^ait ^rnif         1              ai¥ "fe wr-^^aaiT
      ^ "yff          % tifsfl 3ftf         1 at^TOT ^ ila aft ^irf) iRa-'^aair atanH aw ^ 1
      ^araar-aaa? (arr.t^r.anT. jfta) arjHMlRd         artt atraTaaraftfeat ai^, ara ■wi^* ar   1
      afhg^Rift Tf ainl aya-^Rri*! ^ ftaffta wh                         a^f aai a^-aa (3fjOT.3nT. Tfta) ar *0 a^ 1
      a^ fed) TRa a "fed! aaur a!t ^ ^or at aamaai aw ^ ^ it, at iRa ^                        aar            aai^ if ^       aafar
      ^ Hn«»> arat ant^ 1
      f^tll aanT ^             etfa %aer a i^idt aaur air i?tapPrar "feaifa saf^ air aata aRia           1
           stPta^ a?a-^fwq»( Wlci^ ^ (n^yi Rar an^        aTart^^aar-air^ (                  v^) if aar ^ RrRsaait^^ Rnt
      liqei <t>i^ afet «<T^c ^ air aata ai^ 1
      a%r aarar ^ % avata. art.t5t1.3aT. Tfta ^tt?ar a>t Tdia^ ^ ayart^ift ariadf ai^ ^t^ 1
                 (3fr.t5a.aaT.) ar ariT ^ ^ aiH1^ ^ •Rfigif air argR asTar ^PiR^d                            1
                                      INSTRUCTIONS TO THE CANDIDATES
  . 1. This Question Booklet is printedin two languages—Hindi andRngllah. Candidates can select any one of the
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          Paper n      Question paper on the Subject opted by the examinee (Q. No. 61-150)
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S/02/2024/A
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1

     llrf'LS




                      T'j?' "^>14 %
                  (SPACE FOR ROUGH WORK)




    S/02/2024/A




M
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51.                                   ^:                  51. Allred-Rochow scale is related to :

      (A)                 "37^                                (A) lonization energy

      (B)                         ^                           (B) Electronegativity

      (C)                                                     (C) Electron affinity

      (D)               "5)^ ^                                (D) Hydration energy


52.          TTRoit -^f -gq           311^ "qr            52. The correct statement about metallic

            (ipr) ^ ^i.'MHldi<ui                 ^             character and ionization energy down the

      •^f                t:                                    group in the periodic table is :

      (A). .3Wft^OT                   t TM' «TTf^             (A),lonization energy increases and
                   'ETHcTT t" I                                     metallic character decreases.


      (B)                 "3)^ <msal ^                        (B) lonization energy increases and
            ^             t I                                       metallic character increases.


      (C)                 "3)^ "^TStTt ^ cfSTT '^iRq'^i       (C) lonization energy decreases and
                                                                    metallic character decreases.


      (D)                 ^           t          snf^         (D) lonization energy decreases and
            ipjl          i I                                       metallic character increases.


53. 02"^ ^                        ^              ^ 53. The bond order and magnetic character
      t:                                                       of O2"'' is :

      (A) 3 ^sn                                                (A) 3 and diamagnetic
                                                                      y         .     ■ .
      (B) 2.5^^                                                (B) 2.5 and paramagnetic

      (C) 2^S7T                                               ,(C) 2 and paramagnetic

      (D) 2.5 ^2TT yPd^Hchl^                                   (D) 2.5 and diamagnetic

(5)S/2/2024/A                                                                                       P.T.O.
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54.                   0=C=N PiHPdR^d        ^    54. Which of the following cynate ion

  '          1?T«T a;TTI#?^^^ff^ t ?                  0=C=N is isoelectronic with ?


      (A) CO2                                         (A) CO2

      (B) NO2                                        (B) NO2

      (C) SO2                                        (C) SO2

      (D) H2O                                        (D) H2O


55. 6-^T^-                         (3Tj?f5zim)   55. The 8-bond is formed via the overlapping

      ^       "I I                                  . of:


  ■ (A)           uan                                (A) d^_^ and d^ ^2 orbitals

      (B)     cI«TI                                  (B) d^^ and d^^ orbitals

      (C)    ^an d^                                  (C)' d^ and d^ orbitals

      (D) dy,^d^                                     (D) dy^ and dy^ orbitals

56. >FifMw            ^      S-S         ^ 56. Which of the following does not contain

      t ?                                             S-S Linkage ?

      (A) H2S2O3                                     (A) H2S2O3

      (B) H2S2O4                                     (B) H2S2O4

      (C) H2S2O5                                     (C) H2S2O5

      (D) H2S2O7                                     (D) H2S2O7

(5)S/2/2024/A
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65.                              "f^ :■                        65.   Consider the reactions :
                                                       I



      (i) [Cr(H20)6]2+ 4- [Co(NH3)5CI]2+                        .    (i) [Cr(H20)6]2+ 4- [Co(NH3)5C1]2+
            +             ^ [Co(H20)6]2+ +                               4- 5H3O+ ^ [Co(H20)6]2+ 4-
                          [Cr(H20)5Cl]2+SNH/                                         [Cr(H20)5Cl]2+ 5NH4+

      (ii) [Fe(CN)6]4-' +             [Mo(CN)8]3-                    (ii) [Fe(CN)6]4-      4-   [Mo(CN)8]3-
                                                                             ^[Fe(CN)6]3-4-[Mo(CN)8]4-
                ^ [Fe(CN)6]^"+[Mo(CN)8]4-
                                                                     Which one of the following is the
                      ^                      ^ t ?
                                                                     correct statement ?
      (A)       (i)       (ii) a#r1%^TTT? STRffw
                                                                     (A) Both (i) and (ii) involve an inner
            ^               ^ t l
                                                                         sphere mechanism.
      (B)       (i)       (ii)                             ^
                                                                     (B) Both (i) and (ii) involve an outer
            feTM«T ^ t l
                                                                         sphere mechanism.
      (C)             (i) 3TRfe
                                                                     (C) Reaction (i) follows inner sphere
                           (ii) W ^ Psb-MlPciR?
                                                                         and reaction (ii) follows outer
            ^ t I                                                        sphere mechanism. .
      (D)             (i) ^               Psb^lP^P^T                 (D) Reaction (i) follows outer sphere
                      (ii) STRTfW ^                                      and reaction (ii) follows .inner
            ^ t I                                                        sphere mechanism.

66. [Re(CH3)8]2-                 i:                            66. [Re(CH3)8]2"~ contains :
      (A) ^ Re ^ iT«zT                                               (A) Single bond between two Re

      (B) ^ Re ^ tT«2T                                               (B) Double bond between two Re

      (C) ^ Re ^ TT«2I                                               (C) Triple bond between two Re
                                                                                                      \


 ' (D) ^ Re ^                                                        (D) Quadruple bond between two Re

(5)S/2/2024/A                                                                                         P.T.O.
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67. mIPHjRh t :                                           67. Poiphyrin is a :

       (A)                          Ri'l^-s                   (A) Monodentate Macrocyclic Ligand

       (B)                        Pd'lu^                      (B) Bidentate Macrocyclic Ligand

       (C)        ^                                           (C) Tridentate Macrocyclic Ligand

       (D)            o[?^ -q^iln RiA^s                       (D) Tetradentate Macrocyclic Ligand

68.             37^ S^            ^Qlc^ilPlcti "f^^^TRT   68. In weak and strong fields the (CFSE), Aq
             ^ 3WT ^            (CFSE), Aq stiH^!i:            for a metal ion with cfi electronic
      ^t ;                                                     configuration are respectively :

       (A) 0.0 Aq and 1.0 Aq                                  (A) 0.0 Aq and 1.0 Aq
       (B) 0.0 Aq and 2.0 Aq                                  (B) 0.0 Aq and 2.0 Aq
       (C) 2.0 Aq and 0.0 Aq                                  (C) 2.0 Aq and 0.0 Aq
      . (D) 1.0 Aq and 0.0 Aq                                 (D) 1.0 Aq and 0.0 Aq

69.           3Tm [Co(NH3]5N02]2+                 w       69. The complex ion .[Co(NH3]5N02]^"^
      ^ ^^iiq^qai <\5fi[ai t" ?                                shows which type of Isomerism ?

      (A) Pn'ei)^ ti*iiq<Hqai                                 (A) Linkage Isomerism

      (B) y^lPlI^                                             (B) Opitcal Isomerism

      (C)                                                     (C) Hydrate Isomerism

      (D)           WTT^WTT                                   (D) lonisation Isomerism

70. (r-BuCP)4 ^                            t:             70. The cage structure of(/-BuCP)4 is :
      (A)                                                     (A) Layer structure

      (B)                                                     (B) Tetrahedral structure

      (C) of^ 'y*<4HI                                         (C) Cubane structure

      (D)                                                     (D) Cyclic structure

(5)S/2/2024/A
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71. "SwTf ^       -^f 1 amu ^ tTR                 71. In terms of energy the value of 1 amu is
   -i[m i :                                             equal to :

    (A) 931.5                    ■    ■                 (A) 931.5 ergs

 '.(B) 931.5 J(#)                                       (B) 931.5 J

    (C) 931.5 kcal                                      (C) 931.5 kcal

    (D) 931.5 MeV                                       (D) 931.5 MeV


72. 4-31Fl^ 41M4^1h          3Tf^ WR (S)          72. In 4-iron ferredoxins, the number of
    Wn^a^ ^8TT                    ^ WT
                                                        labile S-atoms and cysteine ligands is :
          t:
                                                        (A) 3 and 3            (B) 4 and 3
    (A) 3 afk 3 ,       ■ (B) 4 afk 3
    (C) 4 alk 4          (D) 3 ak 4                     (C) 4 and 4            (D). 3 and 4


73. aqMkRMf^         (Mb02)                       73.   The       magnetic       behaviour      of

    a^TRftftiNrWr (Hb02) ^                              Oxymyoglobin           (Mb02)          and

    ^11^ ^ t :                                          Oxyhaemoglobin (Hb02) is :

    (A)              ^81T yPd^Hchl'M                    (A) Diamagnetic and Diamagnetic

    (B)              ^«1T                               (B) Paramagnetic and Paramagnetic

    (C)              ^8TT HPd-^H=h1'4                   (C) Paramagnetic and Diamagnetic

    (D)              "d^TT                              (D) Diamagnetic and Paramagnetic

74. 60 MHz R ^4lPeld                       ^      74.   In a spectrometer operating at 60 MHz

    NMR "ftFTdT IMS ^                '^* 120 Hz         an NMR signal appears at 120 Hz with
    R 31^ ^ t y 6-^ •^* xmf^                            reference to TMS. The value of chemical

                                                        shift in 6 unit is :

    (A) 2                (B) 1                          (A) 2                  (B) 1

    (C) 0.1              (D) 0.2                        (C) 0.1                (D) 0.2

(5)S/2/2024/A                                                                                 P.T.O.
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75. The analysis method >vhich" does not

  .   fcj^c^Nui ?TTf^^^t :                                     involve the wet chemical analysis is ;

      (A)                                                     (A) Spectrophotometry

      (B) 4dl<Wc[l ,(Mfd^lPklfHRl)                            (B) Fluorimetiy

      (C) Mltr^<liJI4>1                                       (C) Polarography

      (D)                                                     (D) Emission spectroscopy

76. H2O ^^                                      i{        76. How many nuniber of fundamental
      fepft wn -^f T^np               aiT^ ^                   vibrational frequencies are present in the
                                                               infrared absorption spectrum of H2O
      t ?
                                                               molecule ?
      (A) 1                 (B) 2                             (A) 1                (B) 2
      (C) 3                 (D) 4                             (C) 3                (D) 4

77. PHHrdfed          ^^            ^ MT^4ld<             77. Among the following nuclei which does
      ii[^^                       "^iTdT f :                  not act as Mossbauer nuclei is ;

      (A) ^7zii             (B) 59co                          (A)                  (B) 5900
      (C) 57Fe              (D)                               (C) 57Fe             (D) "9Sn

78.                         ^ ?TTfW            -aft       78. The     metals ' involved    in   enzyme

                n^^1ch<u|           ^f ;                      nitrogenase used for nitrogen fixation

                                                              are:
      (A) Fe cWT Mg
                                                              (A) Fe and Mg
      (B) Mo^ Fe
                                                              (B) Mo and Fe
      (C) Mo         K
                                                              (C) Mo and K

      (D) FeTTs^T K                                           (D) FeandK

(5)S/2/2024/A                                         8
MP SET 2024 question paper, State Eligibility Test 2024, Chemical Sciences, page 11 of 36
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79. Pi^^Ripan                         ■                   79. Match the following :
                                                                    Nuclear Methods           Applications

      (a) -HTsh^iJI           (i)         ^ aHE                (a) Activation .       (i)     Age of plants

             \kH^m                                                  Analysis

                              (ii) 6i5^1«ii                    (b) Nuclear .          (ii) Hydrogen
  ,(b)
                                                                    Fission                   Bomb

                                                               (c) Nuclear            (iii) Atom Bomb
      (c)                     (iii)
                                                                    Fussion
         ■




                                                               (d) Carbon Dating (iv) Determination
   ■ (d)                      (iv)
                                                                                              of trace
                                              "dc^
                                                                                              quantities of
                                                  '




                                                                                              elements
             (a)      (b)      (c)        (d)                       (a)       (b)      (c)           (d)
      (A) (iv)        (iii)    (ii)       (i)                  (A) (iv)       (iii)    (ii)          (i)
      (B) (ii)        (iii)    (i)        (iv)                 (B) (ii)       (iii)    (i)           (iv)
      (C) (iii)       (ii)     (i)        (iv)                 (C) (iii)      (ii)     (i)           (iv)
      (D) (i)         (iv)     (ii)       (iii)                (D) (i)        (iv)     (ii)          (iii)

80.                             ■^*                   ^   80. In a nuclear reactor, oxides of which of
      afefn^ im ^TTOt ^ ^                         "51^        the following metals are used as fuel
^ t ?:                                                        " materials ?

      (1)                                                      (1) Uranium

      (2) «i\fWT                              '       ■        (2) Thorium

      (3)                                                      (3) Actinium

      (4)                                                      (4) Plutonium

      (A) (1) 3^ (3)                                           (A) (l) and(3)
      (B) (2) ^ (3)                                            (B) (2) and (3)

      (C) (2), (3) alk (4)                                     (C) (2), (3) and (4)

      (D) (1), (2) alk (4)                                     (D)- (1), (2) and (4)

(5)S/2/2024/A                                                                                              P.T.O.
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81." -m 'Tff^        mra x= 0          x = 2n        81. Which one of the following wave
       Pi*^RiRsici                     chln-Hi to          functions        is   acceptable     in    wave
                                                            mechanics in the range x =                0 to
             W t?
                                                           x = 2% 1 '
      (A) tan X            (B) cosec x
                                                           (A) tan X               (B) cosec X
      (C) sec ;c           (D) sin ;c                      (C) sec X               (D) sin X

82.              TO ^h1c^i<ui ;                       82. In the SchrOdinger wave equation :

             VV+^(E-V)v =0^-,                                      i-jiStI 772 /t-i * t\
                                                                   V>+-p-(E-V)ii/        =0^
      VKf^             t: •                                V represents :

      (A) "^rf^ "3?^ ■                                     (A) Kinetic energy

      (B)                                                  (B) Potential energy

      (C) ^                                               (C) Momentum

      (D) ^                                               (D) Velocity


83.              ^ cR^ ^crii :                        83. The normalization constant A for a given

                                                           wave function :
            u/f;c)= Acos—
            ^^         2a'
      ^ -a<x<a t, ^ ferr                                        \if(x)= Acos—
                                                                     ^     2a'
              A^ ^^ :                                      where          -a<x<a     will      have   the

                                                           value :

      (A)
            ra                    v!                      (A)
                                                                   1                     ■ 2




      (O f                (D) ^/^
                                                          (C) Ji                   (D) ^
(5)S/2/2024/A                                    10
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84.              :                                          84. In the equation :

                                                                           Sn^m
            VV+^(E-V)m/=0                                               vV+-^(b-v)m/=o

                        "t' :                                          is known as :



      (A)                                                        (A) Laplacian operator


      (B)                                                        (B) Hamiltonian operator


      (C)                         WW                             (C) Angular momentum operator


      (D)                                                        (D) Energy operator


85. "qsF             #TT^                 ^ clS^ST 37^^     85. The expectation value of x in a linear
      ■^' X ^ WnfWi "HH t :                                      harmonic oscillator in the groimd state is :
                         /        >^1/4   _ar'                                     ^l/4■ -or'
                             cc
      (f^ t M^o =                                                (Given Vo = —                  )
                         V7C/                                                   \T^/

      (A) 0.50                       (B) 0.25                    (A) 0.50               (B) 0.25

      (C) 0.10                       (D) 0                       (C) 0.10               (D) 0

86.         ^                ^*cbK4) t :                    86. The operator associated with energy is :

            •t 5
      (A)
      ^         5/                                          ' (A) '»!
                                                                          f.2
      (B) -^V'+V                                                 (B) -—V^+V
                                                                 ^ ^     2m


      (C)            (A) 3?k (B)                                 (C) Both (A) and (B)


      (D) H cit (A) 3lk H                        (B)             (D) Neither (A) nor (B)

(5)S/2/2024/A                                          11                                             P.T.O.
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91. HCl,NO,CO, CI2, A C2H4 ^              91. Among HCI, NO, CO,CI2 and C2H4, the
                    t:                        microwave active species are :

      (A) CO, CI2                             (A) CO, CI2
      (B) HCI, NO, CO                         (B) HCI, NO, CO

      (C) CI2, C2H4                           (C) Cl2,C2H4
      (D) NO, CI2                             (D) NO, CI2

92. C-Cl, C-Br, C-C, C-O ^ C-H ^          92. The order of decreasing vibrational

                      ^      "giTT ^ :        frequency for C-Cl, C-Br, C-C, C-O and
                                               C-H is ;
      (A) C-H, C-C, C-O, c-ci, C-Br
                                              (A) C-H, C-C, C-O, C-Cl, C-Br
      (B) C-Cl, C-Br, C-C, C-H, C-O           (B) C-Cl, C-Br, C-C, C-H, C-O.
      (C) C-O, C-H, C-Br, C-Cl, C-C           (C) C-O, C-H, C-Br, C-Cl, C-C

      (D) C-Br, C-CI, C-C, C-O, C-H           (D) C-Br, C-Cl, C-C, C-O, C-H,      .

93. "OT         W:         ^t :           93. Raman spectra is often hampered by :

      (A)       ^                             (A) Fluorescence

      (B)           ^                         (B) Phosphorescence

      (C)        ^                            (C) Infrared

      (D)                                     (D) All of the above

94.         feiFT ^                       94., The Enthalpy of a system is defined by
                    t:                         the relation :

      - (A) h = e;+pv                         (A) H = E + PV ■                    ■

      (B) H = E-PV                            (B) H = E-PV

 ■ (C) E = H + PV '                           (C) E = H + PV

      (D) PV + E.-H                           (D) PV + E - H

(5)S/2/2024/A                            13    .                               P-T.O.
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95.         dIMHH                   ^                    95. The temperature at which two conjugate
             "0^^ 1^ "TO                   °Fi0^M             solutions merge in one another is called:
      t:
                                                              (A) Critical temperatiu-e
      (A) dilPdd) ^
                                                              (B) Critical solution temperature
      (B) shlP-dch                 cIN
                                                              (C) Distillation temperature
      (C) 3Tmf^ 'm

      (D) "Sl^                                                (D) Dalton's temperature


96. 1^               ^                   "srwrfwi        96. The thermodynamic probability of a

      yi^Rtidi        t:             ■                        system in equilibrium is :

      (A) srfecR •                                            (A) Maximum

      (B) %cFT               ■1 ^        '■^'                 (B) Minimum but not equal to 1

      (C)                                                     (C) 1

      (D) ^                                                   (D) Zero


97.   ^          "51^       3TOT            8?R          97. When a strong acid is titrated against a

      a^^rnto 1^ -SM t," cft aTci 1^ TR                       strong base, the end point is the point

 . ^t :                 ■                                     of:


      (A) ^ -dlddidl                                        • (A) Zero conductance

      (B) arfecR MM^hdl                                       (B) Maximum conductance

      (C)            -dld^dl                                  (C) Minimum conductance

      (D) <14^^             ^ ^ "^T^*                         (D) None of the above

(5)S/2/2024/A                                       14
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101.         fsak ^ ^                   ^ 75%         101. For a second order reaction the time

       smfei ^                         ^3^ aT;^
                                                           required to decompose 75% is related to
       3iia*M ?i/2 ^ ■f^i'^iif^ T!^ ^
                                                           its half-life period ty2 by a factor :
       t.:
                                                           (A) 1                (B) 2
       (A) 1               (B) 2

       (C) 3               (D) 4                           (C) 3                (D) 4


102. rHHrdPteld       ^ %1T                ^ f^       102, For which of the following processes

       3i'd<rH+14 TOT (ISC)                t ?             Intersystem Crossing GSC) is essential ?

       (A) yld^lPkl                                        (A) Fluorescence

       (B)                                                 (B) Phosphorescence

       (C) irapfe                                          (C) Chemical luminescence


       (D) ^fe4l«rst>4 ^                                   (D) Radioactive decay


103. ■^33n|TT -sgtfer aiWIi^ ^ 4i^=i)rdti-^           103, In the Michaelis-Menten mechanism for

       rsbyiPciRl :                                        an enzyme catalyzed reaction :

             E + S;?^BS—^P +E •^•,                              E + S:;4=^ES—^P + E
                                                                        *2


                                                          what is the value of Michaelis constant ?
             k,+k.                  k, .                        h+L
       (A) -IT             (B)   A, +^2
                                                          (A) -ir               (B) k^+k2

             ih+h                                                                       +^2
   ,(C)                    (D)
                                   h                      (C)                   (D)
                                                                                      . k.

(5)S/2/2024/A                                    16
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108, What percentage of light will be
108. iRim ^                     ^       ^
                                                           transmitted through two     cells put
       feHT          TOTT        #1T,       "3™
                                                           together in the path of light if their

       WWm              60% T[^ 30% t ? .                  individual transmissions are 60% and

                                                           30% ?
       (A) 18%                (B) 36%
                                                           (A) 18%            (B) 36%

       (C) 54%                (D) 90%
                                                           (C) 54%            (D) 90%


109.                        ^                      109. The theory of multilayer adsorption can
       1^* ^ fer                                           be explained by which of the following

       t?                                                  curves -i



       (A)          "^rorft                                (A) Langmuir isotherm curve

       (B) ii)*^rd-4 ^rorit ^                              (B) Freundlich isotherm curve

       (C) ^.t^. ■^ITOTt ^                                 (C) B.E.T. isotherm curve
  ;
       (D)       "Hwit ^                                   (D) Hemy isotherm curve


110.          Pci-^dH ^ ^ 4)^dldl t :                  110. The square of standard deviation is
                                                           called:
       (A)
                                                           (A) Variance
       (B) MRj^^dl
                                                           (B) Precision

       (C) W«f3I                                           (C) Accuracy

       (D) "^nsfe                                          (D) Significant figure

(5)S/2/2024/A                                     18
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113.                                 ^                   113, The configuration at the two stereogenic
                                                              centres in the compound given below is :

                         CR                                                   CR

               Br                H                                     Br              H


               H                C1                                     H              C1


                         CH,                                                   CH,


       (A) 2S, 3R             (B) 2S, 3S                      (A) 2S, 3R            (B) 2S, 3S

       (C) 2R, 3R             (D) 2R, 3S                      (C) 2R, 3R            (D) 2R, 3S

114. PHMPdRdd a#Tf^ t :                                  114. The following reaction is ;

 o                       o                                O                     O

        (i) Me^CuLi                                            (i) Me^CuLi
         (ii) R/HjO                                             (ii)H*/H,0          '"^CH, ^
 CH3                     CH3
                         95%                                                   95%             5%


       (A)                                                    (A) Racemic synthesis

       (B) dW^R-ijl^eir+icj                                   (B) Diastereoselective

       (C)                                                    (C) Enantiospecific

       (D)                                                    (D) Enantioselective

115. 6.5 g (+)-2-®^^#T          3.5 g (-)-2-®^iiTci      115. Calculate the enantiomeric excess(ee)and
                                                              the specific rotation of a mixture
                "ejuRt            ^i^Mi     =t)lp3ik.         containing 6.5 g of (+)-2-butanol and
     (W (+)-2-®^^HTd ^ fsffW                      +           3.5 g of(-)-2-butanoI(the specific rotation
     13.5° t) :                                               of pure (+)-2-butanol is + 13.5°):
       (A) 20%, + 2.7°        (B) 30%,+ 2.7°                  (A) 20%, + 2.7°       (B) 30%, + 2.7°
       (C) 20%, + 4.05° (D) 30%,+ 4.05°                       (C) 20%, + 4.05° (D) 30%,+ 4.05°

(5)S/2/2024/A                                       20
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J   '   •




121.                            4                                     121. Ketene is reaction intermediate in which

       iT«2ra?!f t ?                                                       rearrangement ? '                                     !
      . (A) ciTcMi                                                        (A) Wolf             •

       (B)                             '                                  (B) Stevens

' (C)                                                                     (C) Wagner-Meerwin                           -


       (D) rmi*Tjd-r4Hi+idH                                               (D) Pinacol-Pinacblone
\                           ■                 .k '                         I                   '           '                     I '
122..i^ a#Tf^ ^ 37(5^ -^fqR f ':                                      122. The end prodiicts of Wittig reaction are :
                                                                                                   s   •   "                     '

       (A)           OT-,                  4)T-M+1h                       (A) Alkane and Triphenyl phosphine
                                                                                                                                 i
                                                                              oxide                     ^
       (B)              H87T                      .inwhT                  .'■      " ' ■    "    .       !
                                                                          (B) Alkene and Triphenyl phospliine
             ^m\i4
                                                                                                                                 j
                                                                                   oxide                                         1
       (C) ij.^lH ^8TT                                wrft^
                                                                           (C) Alkyne ^d Triphenyl phosphine
             37^^ '              ..                   .       •                .   ,       .       .           .                 i

                                                                                   oxide                                         I
                                                                          '            •                           '             r




       (D) cjiqci                                37OTI^                   (D) Only Triphenyl phosphine oxide


123.                 37f«rfsF^ ^ 37f^                                 123. The final product of Reimer-Tiemann

       t.:                                                                 reaction is :


       (A) -Sfei^IJErsei^-s                                                (AX Salicyldehyde
  /      •     '

       (B)                      37t^                                       (B) ■ Salicylic acid

       (C)                                                              : (O) Ethanol                                      -   ' r


       (D)                                                                 (D) Phenol

(5)S/2/2024/A                                                     23                                                           P.T.O.
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124.                    "3^ 351ch ^                 ^     124. The correct stability sequence of simple
                ^          7                                   alkyl free radical is :

                                      H         CH,                                       H        CH,

       (A) CH3 > CH3-CH2 > CH3-C' > CH3-C'                    (A) CH3 > CH3-CH2 > CHyC' > CHj-C'
                                      CH3     , €^3                                       CH,      CH,

                                     H         CH,                                                 CH,
                                      I        'I
       (B) CH3-CH2 > CH3 > CHj-C' > CHa-C'                    (B) CH3-CH2 >         > CH3-C* > CH3-C'
                                     CH3       CH3                                       CH,       CH,


                 CH3       H                                             CH,        H
                 I          I             .    .                                    i
       (C) CH3-C' > CH3-C' >CH3-CH2>CH3                       (C) CHg-C* > CH3-C' >CH3-CH2>CH3
                 I         I
                 CH,       CH,                                           CH3     . CH3

                H          CH,                                                     CH,

       (D) CH3-C' > CH3-C' >CH3-CH2>CH3                       (D) CH3-C'>CH3-C' >CH3-CH2>CH3
                CH,        CH,                                           CH,       CH,


125.           Wi                   -qi        ^ 125. The introduction of alkyl or acyl group
       ^         4)^<rildl t : ■ .                             into an aromatic ring is called ;

       (A)           3#TfeT                                   (A) Perkin Reaction

       (B)              a#?f^                                 (B) Reimer-Tiemann Reaction

       (C) TFtecT-^TNS STf^fel                                (C) Friedel-Crafts Reaction

       (D)^ 3#TfeTT                                           (D) Wurtz Reaction

126. rHMPdPsId                  ^           ^^            126. What is the correct name of the

       t?                                                     following reaction ? .

 > C = O +HjN -NH2 + KOH -^> CH2 + N2                     >C =0+H2N-NH2+K0H -» CH2+N2

       (A)                                                    (A) Dieckmann Reaction

       (B)                                                    (B) Friedel-Crafts Reaction

       (C) ftBiTfeRrt                                         (C) Reformatsky Reaction

   , (D)                  37WPT                               (D) Wolf-Kishner Reaction

(5)S/2/2024/A                                        24
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127.                              127. The reduced product of Cannizzaro's

       t.:                            reaction is :


       (A) 3n8fe                      (A) Primary Alcohol


   - (B) 1%^                          (B) Phenol


       (C)                            (C) Amide


  ■ ,(D)                              (D) Aldehyde


128. rdHPdRsJd      ^             128. Which among these will undergoes

   . 4)Wd1=b{u|     WT   t ? •        Gattermarm-Koch formylation ?




             CH.                             CH,



       (B)[O                          (B) fo

             NMe,                            NMe2


       (C) fo                         (C) I o

             OH                               OH



       (D) 1^-                        (D) I O

(51S/2/2024/A                    25                                   P.T.O.
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129.           X-CH;                        129. The carbanion X-CH^ will be most
        wWl, ^ 'X'        :                       stable when'X' is :


        (A) -NO2          (B) -COCH3             (A) -NO2            (B) -COCH3

     (C) - SOjPh     . (D) - CN                  (C) -S02Ph          (D) - CN


 130. H0CH2(CH0H)4CH0 ^             TRim     130. How many optically active isomers are

                                                  there for HOCH2(CHOH)4CHO ?

    (A) 16                (B) 10                 (A) 16              (B) 10

    (C) 4                 (D) 2                  (C) 4               (D) 2


131. PHHRrlfeld sjMlFzir ^         f:        131. Predict the product in the following

                                                 reaction;

                     Av

                                                       ^        hv      Product




    (A)               (B)
                                                 (A)                 (B)




    (C)               (D)                       (C)                  (D)




(5)S/2/2024/A                           26
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140.                                   "zJtfe CjHgO        140. A saturated open chain compound

       2950 cm-^ -qr IR fe                       t,             CjHgO, shows an IR band at 2950 cm~^
             3300 cm-^              1720 cm-^ ^^                but   none     near   3300   cm"^   and

                        ^ I "q?" 4inich t" :                    1720 cm~^ The compound is :

       (A)                                                      (A) Carboxylic acid

       (B) "#5^                                                 (B) Aldehyde

       (C)                                                      (C) Ether

       (D)                                                      (D) Ketone


141. p-Hl^4*r?l^4^f^H (P-CD)                               141. How many glucose units are present in

              ^t ?                                              p-Cyclodextrin (P-CD) ?

       (A) W                       (B) "qN                      (A) Seven             (B) Five

       (C) SRig                (D) ■^:                          (C) Eight             (D) Six

142.                          TR*ir3 ^                     142. Quantum Dots are comprising of how
       f ?                                                      many atoms ?

       (A) 100-200                 (B) 2-lb                     (A) 100-200           (B) 2-10

       (C) 200-10000               (D) lOOOO-lOOOOO             (C) 200-10000 -       (D) 10000-100000

143. 1^ 3fTOT5^ ^Hicb4 ^ ^3q4q ^ t:                        143. Zinc oxide nanoparticles are used in :

       (A)        "^f                                           (A) Catalyst

       (B)                    •#                                (B) Antibacterial

       (c)              ■^*                                     (C) Antiseptic

       (D) "^q^ ^                                               (b) All of the above

(5)S/2/2024/A                                         30
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144.                      ^       #7        %          144. Which of the following is not a Green
              t ?                                           House Gas ?

       (A) -Rt^                                             (A) Methane

       (B)            aWETT^                                (B) Nitrous oxide

       j[C)                                                 (C) Carbon dioxide       , ,

       (D) ^TI^NfT                                          (D) Hydrogen

145. «hHs^          Iq^Tjici    ^ 1^ PiHRnRaa          145. Which of the following is used as a
       ■^f    '^mi                     TO "SiH^             green solvent for bleaching clothes ?
       ^ t ?                                                (A) Hydrogen peroxide
       (A) ^T1#FT
                                                            (B) Tetra cWoroethane
       (B) t$r
                                                            (C) Benzene
       (C) Mt
                                                            (D) Toluene
       (D)
                                                       146. Who is called the father of supra-
146.          37^ WHfWr ^              ^ TOT
                                                            molecular chemistry. ?
       «TRTT "t ?
       (A) "#7-^                                            (A) Jean-Marie Lehn

       (B)       sTftnr                                   ' (B) K. Arigga

       (C)           ^                                      (C) PJ. Craig

  .    (D) TOT                                              (D) Hermann Dugas

147. ^                                  ^              147. The removal of hazardous substances^ and
                       ^ 3PitR ^ TO^ t :                    pollutants from soil by microorganism is
                                                            called :
       (A)            ©111 ■
                                                            (A) Biofiltration
       (B)            Pisii
                                                            (B) Bioremediation
       (G)            TTfe^TO                               (C) Biomodelling
       (D) -SR^ "^TRt                                       (D) All of the above

(5)S/2/2024/A                                     31                                          P.T.O.
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148.          ^ wftn                t:              148. Caffeine is used as :


       (A)                ^         ^ ^ '^*             (A) Cent^ nervous system stimulator


       (B)                  ^       "^f                 (B) Cortical stimulator
                                            r




       (C)                ^ ^ -^f                       (C) Bronchodilator ,.


       (D)                                              (D) All of the above


149. 3?!^             ^             t:              149. Drug dissolution rate is dependent on :


       (A)         ^^                                   (A) The water solubility of the drug


   ■ (B)           ^ pH ^                               (B) The pH of the medium


       (C) ate ^ pKa"q^.                                (C) The pKa of the drug


       (D)                                              (D) All of the above


150. rHHRriP^d        ^                         ^   150. Which of the following statements is not

       1^ ^^ t ?                                         true for sorbitrate ?

       (A) "q?" ctiiK^lqi^crK affqfl? ^ aHPfer
             aqicft t I                                 (A) It comes under c^diovascular drugs.

       (B) "T? arfq;^         ^i4 cfT(.^ <^iQii         (B) It is a long acting antianginal agent.

                                                        (C) It is metabolized primarily in the
       (C)      "3^ ^                     w#Tcr
             ^t I ^                                           liver.

       (D)                ^^ "SWT •^* ^
                                                        (D) It uses'in the treatment of cancer.
             t I

(5)S/2/2024/A                                     32
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S/02/2024/A
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■V'S




              (SPACE FOR ROUGH WORIQ




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Source: Madhya Pradesh Public Service Commission. Question paper published by Madhya Pradesh Public Service Commission.

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