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Catalysis and Catalytic Reactors Questions and Answers

21.

Consider the following statements about slurry reactors.
1. Fine particles give a high effectiveness factor.
2. Separating catalyst from product is a real difficulty.
3. They are used mainly for gas phase reactions.

Answer: A

Correct answer: 1 and 2 only

Statements 1 and 2 are correct: the very fine particles used in a slurry give short diffusion paths and effectiveness factors near unity, and filtering that fine solid out of the product is one of the process’s real difficulties. Statement 3 is wrong - a slurry reactor holds catalyst suspended in a *liquid*, and is used for three-phase reactions such as hydrogenations, with the gas sparged through.

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22.

Pressure drop through a fixed bed rises steeply if the particles are made smaller, which creates

Answer: B

Smaller particles help the chemistry and hurt the hydraulics, so the size is a compromise. Shaped catalysts such as rings and trilobes are made to improve the trade-off between the two. Particle size is always a compromise.

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23.

Assertion (A): Catalyst pellets are made in shapes such as rings and trilobes rather than simple spheres.
Reason (R): Such shapes give a short diffusion path without the pressure drop of a small sphere.

Answer: C

Both are true and the reason gives the design objective, and it is a good example of a geometric solution to a conflict between two physical requirements. Void fraction rises with the shaped forms. Geometry solves a conflict the chemistry cannot.

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24.

A catalyst loses half its activity in 6 months of operation. If the decay is first order in activity, what fraction remains after a year?

Answer: D

Two half lives leave a quarter of the original activity. Catalyst life is usually described this way and sets the interval between charges or regenerations. First order decay halves it each period. Two half lives leave a quarter behind.

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25.

State whether the following is true or false.
Catalyst deactivation is usually allowed for by raising the temperature over the run.

Answer: A

The extra rate compensates for the lost activity and holds conversion steady, and the end of run temperature is what limits the cycle. Raising it too far accelerates sintering and coking further. End of run temperature limits the cycle.

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Answer: B

The straight channels let the exhaust pass with little resistance, which matters greatly to engine performance. Its surface area per unit volume is lower than a packed bed and it is not cheap. Back pressure is the overriding constraint.

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27.

Assertion (A): A monolith is chosen for an automotive catalyst despite its lower surface area per unit volume.
Reason (R): Back pressure on the engine is the overriding constraint.

Answer: C

Both are true and the reason gives the priority: a packed bed of the same activity would restrict the exhaust unacceptably, so the geometry is chosen for the hydraulics rather than the chemistry. Straight channels give a clear path.

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