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Chemistry Questions and Answers

452.

The heat required to raise the temperature of body by 1 K is called

Answer: B

This is the thermal capacity, or heat capacity, of the body.

\[C=\frac{Q}{\Delta T}\] measured in \(\mathrm{J\,K^{-1}}\). It depends on the mass of the particular body. Specific heat is the heat needed per unit mass for the same rise, and is a property of the substance rather than of the object.

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453.

Which one of the following metals does not react with water to produce Hydrogen?

Answer: C

Cadmium does not liberate hydrogen from water.

Sodium, lithium and potassium are all alkali metals, high in the reactivity series, and react with even cold water. Cadmium lies below hydrogen in the series and is unaffected by water at ordinary temperatures.

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454.

Which of the following gases is the most toxic?

Answer: D

Carbon monoxide is the most toxic of these.

It binds to haemoglobin about 240 times more strongly than oxygen does, forming carboxyhaemoglobin, so the blood can no longer carry oxygen. A few hundred parts per million can be fatal, and because the gas is colourless and odourless there is no warning.

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455.

The half life period of an isotope is 2 hours. After 6 hours what fraction of the initial quantity of the isotope will be left behind?

Answer: C

One-eighth of the isotope remains.

\[\text{number of half-lives} = \frac{6\ \mathrm{h}}{2\ \mathrm{h}} = 3\]

\[\frac{N}{N_0} = \left(\frac{1}{2}\right)^{3} = \frac{1}{8}\]

The quantity halves at 2 h, quarters at 4 h and falls to an eighth at 6 h.

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456.

pH of water is

Answer: C

The pH of pure water is 7 at 25 °C.

Water self-ionises to the extent that \[[\mathrm{H^+}] = [\mathrm{OH^-}] = 10^{-7}\ \mathrm{mol\,L^{-1}}\] so \(\mathrm{pH} = -\log(10^{-7}) = 7\). The value drifts below 7 at higher temperatures, but the water stays neutral because the two concentrations remain equal.

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457.

Which of the following is used to preserve specimens in the biology laboratory?

Answer: C

Formaldehyde is used to preserve specimens.

Formalin, a 40 per cent aqueous solution, cross-links the amino groups of proteins and so hardens the tissue and kills any bacteria or fungi that would decompose it. Its own pungency and toxicity are the drawback.

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459.

The hottest part of the gas flame is known as

Answer: D

The hottest part of a gas flame is the non-luminous zone.

Where the air supply is plentiful, combustion is complete and the flame burns pale blue at about 1,500 °C. The luminous yellow zone owes its light to glowing unburnt carbon particles and is cooler, because combustion there is incomplete; the dark inner zone is unburnt gas and coldest of all.

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460.

Who proposed the first atomic theory?

Answer: C

John Dalton proposed the first atomic theory, in 1808.

His postulates were that matter consists of indivisible atoms, that all atoms of an element are alike in mass and properties, and that compounds form when atoms combine in fixed small whole-number ratios. The theory accounted at once for the laws of conservation of mass and of definite and multiple proportions.

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