Match each effect with what it does to the equilibrium vapour pressure over a droplet.
List I
A. Kelvin curvature effect
B. Raoult solute effect
C. Increasing droplet radius
D. More dissolved solute
List II
1. reduces the influence of both
2. raises it, strongly at small radius
3. deepens the lowering at a given radius
4. lowers it, strongly at small radius
Answer: C
The Kohler curve is simply the product of these two competing influences. Which one dominates depends on the radius, and the crossover is what produces the maximum on the curve. Solute dominates at small radius and curvature governs the approach to the peak.
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