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Free Electron Model Questions and Answers

1.

Crystal structures of two metals A and B are two-dimensional square lattices with same lattice constant a. Electrons in metals behave as free electrons. The Fermi surfaces corresponding to A and B are shown by solid circles in figures.

Two k-space diagrams with a dotted square of half-width pi/a. Metal A: the Fermi circle touches the middle of each side of the square, at (pi/a, 0). Metal B: the Fermi circle passes through the four corners of the square

The electron concentrations in A and B are \(n_{A}\) and \(n_{B}\), respectively. The value of \(\left(\dfrac{n_{B}}{n_{A}}\right)\) is

Exam Year(s)

GATE Physics - 2024,

Answer: B

The ratio nB/nA is 2.

For free electrons in two dimensions the electron concentration is proportional to the area of the Fermi circle, πkF2, so n ∝ kF2.

  • Metal A: the circle touches the zone boundary at (π/a, 0), so kF = π/a.
  • Metal B: the circle passes through the corners of the square zone, at (π/a, π/a), so kF = √2 π/a.

\[ \begin{aligned} \frac{n_{B}}{n_{A}} &= \left(\frac{\sqrt{2}\,\pi/a}{\pi/a}\right)^{2} \\ &= 2 \end{aligned} \]

√2 is the ratio of the Fermi wavevectors, not of the concentrations. 3 and 3√3 would need other radii, and 3√3 a three-dimensional kF3 scaling.

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2.

As per the Drude model of metals, the electrical resistance of a metallic wire of length \(L\) and cross-section area \(A\) is

(Consider \(\tau\) as the relaxation time, \(m\) as electron mass, \(n\) as carrier concentration and \(e\) as electronic charge)

Exam Year(s)

GATE Physics - 2025,

Answer: A

The resistance is \(\frac{mL}{ne^{2}A\tau}\).

In the Drude model an electron accelerated by a field \(E\) gains drift velocity \(v_{d} = \frac{eE\tau}{m}\) between collisions, so the current density is

\[ \begin{aligned} J &= nev_{d} = \frac{ne^{2}\tau}{m}E \Rightarrow \sigma = \frac{ne^{2}\tau}{m} \\ R &= \frac{L}{\sigma A} = \frac{mL}{ne^{2}A\tau} \end{aligned} \]

The other options carry spurious factors of 2 or 4 that the Drude derivation does not produce: the resistance is simply the length over conductivity times area.

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3.

Consider one mole of a monovalent metal at absolute zero temperature, obeying the free electron model. Its Fermi energy is \(E_{F}\). The energy corresponding to the filling of \(\frac{N_{A}}{2}\) electrons, where \(N_{A}\) is the Avogadro number, is \(2^{n}E_{F}\). The value of \(n\) is

Exam Year(s)

GATE Physics - 2025,

Answer: A

The value is \(n = -\frac{2}{3}\).

In the free electron model the Fermi energy depends on the electron density as \(E_{F} \propto N^{2/3}\) (for a fixed volume), since \(E_{F} = \frac{\hbar^{2}}{2m}(3\pi^{2}N/V)^{2/3}\). Filling only half the electrons gives

\[ E = E_{F}\left(\frac{1}{2}\right)^{2/3} = 2^{-2/3}E_{F} \]

so \(n = -\frac{2}{3}\). The energy must be less than \(E_{F}\), which rules out \(+\frac{2}{3}\); \(-\frac{1}{3}\) and \(-1\) use the wrong power of the density.

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4.

The Fermi-momentum and dimension of a mono-atomic 2D square crystal are given by kF and L. If each atom is contributing one electron to the Fermi gas, the size of the primitive cell is :

Exam Year(s)

MH SET - 2018, SET Exam - 2018,

Answer: A

The primitive cell has area \( \frac{2\pi}{k_{F}^{2}} \).

In two dimensions each \( k \)-state occupies an area \( (2\pi/L)^{2} \), and each holds two electrons. Filling a Fermi circle of radius \( k_{F} \):

\[ \begin{aligned} N &= 2 \times \frac{\pi k_{F}^{2}}{(2\pi/L)^{2}} = \frac{k_{F}^{2}L^{2}}{2\pi} \\ \frac{L^{2}}{N} &= \frac{2\pi}{k_{F}^{2}} \end{aligned} \]

With one electron per atom, N is also the number of atoms, so \( L^{2}/N \) is the area of one primitive cell. \( \pi/k_{F}^{2} \) forgets the spin factor of 2, and the options containing L grow with the size of the crystal, whereas the area of one cell cannot depend on L.

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5.

Density of states in conduction band for electrons assumed to be essentially free in two dimensions is proportional to :

Exam Year(s)

MH SET - 2018, SET Exam - 2018,

Answer: B

In two dimensions the density of states is independent of energy.

The number of states with energy below E is proportional to the area of the circle of radius \( k \) in k-space, \( \pi k^{2} \), and \( E = \hbar^{2}k^{2}/2m \) makes \( k^{2} \propto E \). So N(E) grows linearly with E and its derivative is constant:

\[ g(E) = \frac{mA}{\pi\hbar^{2}} \]

for area A including spin. \( E^{1/2} \) is the three-dimensional result and \( E^{-1/2} \) the one-dimensional one.

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