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Cement and Refractories Questions and Answers

41.

A cement of specific gravity 3.15 occupies, for 50 kg,

Answer: A

Correct answer: about 15.9 litres

Volume is mass divided by density, and a specific gravity of 3.15 means a density of 3150 kg/m³: \[ V = \frac{50}{3150} = 0.0159\ \mathrm{m^3} = 15.9\ \text{litres.} \] This is the figure behind the familiar statement that a 50 kg bag of cement occupies about 0.035 m³ loose - the difference between the two being the voids between the grains.

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42.

A refractory brick of bulk density 2.1 g/cm\( ^3 \) and true density 2.8 g/cm\( ^3 \) has a porosity of

Answer: B

Correct answer: 25 per cent

Porosity is the fraction of the volume that is void, given by comparing bulk and true density: \[ P = 1 - \frac{\rho_{bulk}}{\rho_{true}} = 1 - \frac{2.1}{2.8} = 1 - 0.75 = 0.25. \] Porosity matters because it governs how readily slag penetrates the brick and how well it insulates - and those two pull in opposite directions.

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43.

A mortar cube of 50 mm side fails at a load of 100 kN. Its compressive strength is

Answer: C

Correct answer: 40 N/mm\( ^2 \)

The area of a 50 mm cube face is \( 50 \times 50 = 2500 \) mm², so \[ f = \frac{100 \times 10^3}{2500} = 40\ \mathrm{N/mm^2}. \] The commonest error is to forget the conversion of kilonewtons to newtons, which gives an answer a thousand times too small.

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44.

Adding 3 per cent gypsum to 1000 kg of clinker gives ground cement weighing

Answer: D

Correct answer: 1030 kg

The gypsum is added as a percentage of the clinker, so 3 per cent of 1000 kg is 30 kg and the ground cement weighs \[ 1000 + 30 = 1030\ \text{kg.} \] Reading it as 3 per cent of the finished cement would give 1031 kg, a difference too small to matter here but worth being deliberate about in a mass balance.

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45.

Match the compound with what it contributes.

1. Tricalcium silicate   2. Dicalcium silicate   3. Tricalcium aluminate

P. Flash set and the greatest heat   Q. Early strength   R. Later strength

Answer: A

Correct answer: 1-Q, 2-R, 3-P

The three principal compounds divide the work between them. Tricalcium silicate hydrates quickly and gives the early strength. Dicalcium silicate hydrates slowly and supplies the later strength, contributing little in the first week. Tricalcium aluminate gives almost no strength but reacts violently with water, producing a flash set and the greatest heat of any of the compounds.

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46.

Match the refractory with its class.

1. Magnesite   2. Silica   3. Chromite

P. Acidic   Q. Neutral   R. Basic

Answer: B

Correct answer: 1-R, 2-P, 3-Q

The classification follows the chemistry. Magnesite is magnesia-rich and therefore basic. Silica is acidic. Chromite is neutral, which is why it is used as a buffer layer between an acidic and a basic lining where the two would otherwise react. Matching the lining to the slag is the first decision in selecting a refractory.

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47.

Put the zones of a rotary cement kiln in the order the meal passes through them.

1. Clinkering zone   2. Drying zone   3. Cooling zone   4. Calcination zone

Answer: C

Moisture goes first, the carbonate decomposes next, the compounds form at the hottest point, and the clinker is quenched last. In a modern plant the first two stages happen in the preheater and precalciner rather than in the kiln itself.

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48.

Consider the following statements about cement.

1. Gypsum is added to retard setting   2. Tricalcium silicate gives the later strength   3. Cement sets by hydration rather than by drying

Answer: D

Correct answer: 1 and 3 only are correct

Statements 1 and 3 are correct: gypsum retards the flash set caused by tricalcium aluminate, and cement sets by hydration rather than by drying, which is why it hardens under water. Statement 2 reverses the two silicates - tricalcium silicate gives the early strength and dicalcium silicate the later.

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Answer: A

Correct answer: raising the tricalcium aluminate content

Tricalcium aluminate has the highest heat of hydration of all the clinker compounds, so raising it increases the heat rather than reducing it. The other three all reduce it: dicalcium silicate reacts slowly and releases less heat, a pozzolana replaces some of the clinker, and coarser grinding slows the reaction and spreads the heat over a longer time.

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50.

Three of the following are properties required of a working-face refractory. The exception is

Answer: B

Correct answer: high porosity

Porosity is what an insulating refractory needs, not a working-face one. At the hot face, pores admit slag and gas into the body of the brick and accelerate its destruction, so a dense low-porosity brick is wanted there, backed by a porous insulating layer behind it. The other three - spalling resistance, refractoriness under load and slag resistance - are all working-face requirements.

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