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Water Technology Questions and Answers

61.

A water sample's dissolved oxygen falls from 8.2 to 3.4 mg/L over five days at 20 degrees. Its biochemical oxygen demand is

Answer: A

Correct answer: 4.8 mg/L

The biochemical oxygen demand is simply the oxygen consumed during the incubation: \[ 8.2 - 3.4 = 4.8\ \mathrm{mg/L}. \] The five days at 20 °C are the standard conditions, chosen by convention rather than because the oxidation is complete - the test measures a defined fraction of the total demand, which is why the conditions must always be quoted with the result.

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62.

Match the trouble with what causes it.

1. Caustic embrittlement   2. Priming   3. Scale

P. Water carried over with the steam   Q. Free alkali at stressed joints   R. Calcium sulphate deposited on hot surfaces

Answer: B

Correct answer: 1-Q, 2-P, 3-R

Three distinct boiler troubles with three distinct causes. Caustic embrittlement is intergranular cracking where free alkali concentrates in the crevices at riveted or stressed joints. Priming is the carrying over of water with the steam. And scale is the hard deposit left where a salt such as calcium sulphate becomes less soluble at the hot surface and crystallises on to it.

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63.

Match the process with the ion it exchanges.

1. Zeolite softening   2. Cation exchange in demineralisation   3. Anion exchange in demineralisation

P. Hydrogen ion   Q. Sodium ion   R. Hydroxyl ion

Answer: C

Correct answer: 1-Q, 2-P, 3-R

Each process is named by the ion the bed gives up. Zeolite softening works in the sodium form and releases sodium ions in exchange for calcium and magnesium. In demineralisation the cation exchanger is in the hydrogen form and the anion exchanger in the hydroxyl form, so the two released ions combine to make water and the salts disappear entirely.

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64.

Put the steps of municipal water treatment in order.

1. Filtration through sand   2. Screening of the raw water   3. Disinfection with chlorine   4. Coagulation and sedimentation

Answer: D

Screens take the coarse matter, coagulation and settling the colloidal, the sand filter the remainder, and chlorine is added last so that its residual survives into the distribution system. Disinfecting before filtration wastes most of the dose.

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65.

Consider the following statements about water treatment.

1. Temporary hardness is removed by boiling   2. The zeolite process removes both cations and anions   3. Calgon forms a soluble complex with calcium

Answer: A

The first and third are correct. Zeolite exchanges cations only, so the sulphates and chlorides remain in the water paired with sodium and the total dissolved solids are unchanged. Removing the anions as well requires a hydroxyl-form anion exchanger in series.

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67.

Three of the following are internal conditioning methods. The exception is

Answer: C

Lime-soda is an external treatment applied in its own plant before the water ever enters the boiler. The other three are chemicals dosed into the boiler itself to deal with whatever hardness arrives there despite the external treatment.

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68.

A boiler tube has bulged although the water is soft and the firing is normal. The likely cause is

Answer: D

Correct answer: a deposit insulating that part of the tube

A bulge means the metal reached a temperature at which it lost its strength, and with normal firing the only way that happens is if heat cannot pass into the water. A local deposit - scale or a settled sludge - does exactly that. Soft feed water does not preclude it, since the deposit may be old, or may have come from a carry-over or a leak rather than from hardness.

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69.

An analysis reports both hydroxide and bicarbonate alkalinity in the same sample. The correct conclusion is

Answer: A

Correct answer: the analysis is in error

Hydroxide and bicarbonate cannot coexist in the same solution: hydroxide immediately converts bicarbonate to carbonate and water. A sample may contain hydroxide with carbonate, or carbonate with bicarbonate, but never the first and the last together, so a result reporting both indicates a mistake in the titration or the calculation.

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Answer: B

Correct answer: both the assertion and the reason are true and the reason explains the assertion

Both are true and the reason is exactly the mechanism. Because calcium sulphate becomes less soluble as temperature rises, saturation is reached first at the hottest surface in the boiler, which is the tube wall, so the salt crystallises directly on to the metal as an adherent scale. A salt behaving the other way would precipitate in the cooler bulk water and settle out as sludge.

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