Which statement is the first law of thermodynamics?
Answer: A
The first law is a statement of energy conservation: heat supplied to a system either raises its internal energy or is spent doing work on the surroundings. For a gas the work is the pressure times the change in volume. The second option states the second law, the third is a consequence of it, and the fourth is the equation of state, which is an independent relation. Applying the first law to a parcel of air moving vertically is what produces the adiabatic lapse rate and the whole framework of atmospheric thermodynamics.
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